高分子化学-zhugekk教程方案.ppt

Thank you for your attention * Synthesis of Cu or Cu2O-polyimide nanocomposites using Cu powders and their optical properties JK·Bai 2014000159 zhugekk 文献基本信息 Synthesis of Cu or Cu2O-polyimide nanocomposites using Cu powders and their optical properties Received 14 May 2014, revised 14 July 2014 Accepted for publication 21 July 2014 Published 22 August 2014 Abstract and Keywords Nanocomposites consisting of Cu or Cu2O nanoparticles in various polyimide(PI) films were successfully prepared using polyamic acid(PAA) and Cu powders.Cu powders were dissolved into PAA solutions, and the solutions were spin-coated onto the substrates. Cu or Cu2O nanoparticles were formed in PI film by curing in a reducing or inert atmosphere, respectively.The Cu nanoparticles were transformed to Cu2O nanoparticles by post-heat treatment in an oxidizing atmosphere after curing in a reducing atmosphere. Transmission electron microscopy showed that uniform, round Cu2O nanoparticles 6.0 nm in diameter were dispersed in the PI film by post-heat treatment. The addition of Cu2O nanoparticles in the 4,4′-(hexafluoroisopropylidene)diphthalic anhydride-4,4′-oxydianiline (6FDA-ODA) PI film enhanced the refractive index of the 6FDA-ODA PI film from 1.60 to 1.72 at 633 nm, and the transparency of the nanocomposite film was about 70–90% in the visible region and remained around 90% beyond 550 nm. 1. Introduction 近年来，无机和有机的结合材料越来越受到人们的重视，这是因为它们在很多方面展现出了别的材料不具备的特性。比如在太阳能电池、燃料电池、传感器、涂料、绝缘体等等方面的应用就让它们在众多的材料中脱颖而出。 一个纳米材料的特殊应用在于它的光学特性，因为多聚物的折射率可以和从多聚物基质中提取出来的无机纳米颗粒的相吻合。像SiO2，ZnO，TiO，ZrO2，CeO2，Al2O3和BaTiO3等多种无机纳米特性都可以与它们在聚合物基质上时的纳米特性相吻合。 大多数多聚物在热性能和机械性能上的缺陷导致了它们的应用受到了一定的限制。 PI（聚酰亚胺）是一种非常优秀的纳米复合材料的基质，因为它有很好的热稳定性、化学稳定性、机械特性和低的热膨胀系数。因此，以PI为基础的含有无机纳米粒（如Au、Ag、Cu、SiO2、TiO2等）得到了广泛的应用。也是因为PI-纳米粒薄膜的高折射率，很多的研究都是纳米粒的研究都是根据这点的。本文中研究的氧化亚铜纳米粒也是一种有着高折射率的材料，在波长为633nm时可以达到2.93. 制备以PI为基质的纳米复合材料的方法 1.传统离子培植 2.表面修复和离子交换技术 3.固体凝胶工艺 4.原位合成 各种方法的比较 1.离子培植法 缺点：会损坏纳米粒表面，并且纳米粒 的尺寸不好控制 2.表面修复和离子交换技术 优点：微粒的尺寸，体积分数，纳米复 合材