铁（Ⅱ）%2f二苯乙醇酸催化体系应用于活性聚合反应研究.pdf

Abstract ABSTRACT This paper has studied the development of efficient catalyst system of living free radical polymerization and living cationic polymerization of styrene. In the research work of living free radical polymerization, to discover the novel and efficient catalyst system is a importment aspect. Atom Transfer Radical Polymerization (ATRP) is a novel polymerization method promoted in the recent years. In the reaction of atom transfer radical polymerization, catalyst system plays a crucial role in the control of the polymerization, the exploiture of novel and efficient catalyst system is in the highlight.On the basis of literature research, we find that the differential of redox potential of the catalyst has a range for successful ATRP. Enlightened by that, we connect the selection of catalyst with electrochemistry. Ferrous (II) chloride/ Benzeneacetic acid and Ferrous (II) chloride/Butanedioic acid was adopted as the catalyst for ATRP of styrene, and the effects of many factors on the polymerization were also investigated. Polystyrene with low polydispersity (1.2Mn 1.5) was obtained.The measured number-average molecular linearly increases with the monomer conversation and the plot of ln([M0]/[M]) versus time maintain linear. All these show that the chosen catalyst could catalyze the living/controlled polymerization of styrene.Then we used this catalyst system to Methl Methacrylate,and the prospective result is achieved.It testifies FeCl2/Benzilic acid is a effective catalyst system both styrene and MMA.Transitional metal complexed by acids prove to be effective in ATRP. The paper describe a roughly guideline in the design of catalyst by electrochemistry. Living cationic polymerization was achieved in 1984 by ???? ?,and the same time Kennedy achi