中南大学生分离工程作业汇编.docx

Central South University Separation Process Principles J.D. Seader, Ernest J. Henley 班级：化学工程与技术 学号： 142312131 姓名： 崔东红 指导老师：周涛 Conceptual design aspects of reactive distillation processes for ideal binary mixtures Kai Sundmacher, Zhiwen Qi The combined simultaneous operation of chemical reactions and multicomponent distillation is called reactive distillation (RD) In most cases, the reaction is catalyzed homogeneously or preferably heterogeneously. In some cases, it can replace conventional reaction-distillation sequences or it can be used to complete existing plants in order to lower production costs or to improve the purity of the products. What is presented below is a comparative study on the conceptual design of reactive distillation process configurations, considering the reversible reaction A1=A2 in an ideal binary mixture as simple model system. The analysed flow schemes are a reactor-distillation column sequence with an external recycle loop, the same recycle system with a prereactor, a nonreactive distillation column on top of a reactive reboiler, a fully reactive distillation column, and a hybrid distillation column combining a reactive and a nonreactive section. For these configurations, the design aspects are discussed in terms of the most important operating parameters, kinetic parameters and design parameters The present contribution elucidates the conceptual design of RD processes for the simple reaction A1=A2 in ideal binary mixture. For the purpose of comparison, the attainable product concentration is determined in dependence on the Damko¨ hler number and on the recycle or reflux ratio. Comparing the performance of the considered different reaction-distillation processes, one can conclude that a non-reactive section on top of reactive total reboiler seems to be the best configuration concerning both productivity and reliability of design. The minimum reflux ratio Rmin of this configuration can be easily estimated from the above Equati