C-H键活化,chemicalreview讲课.pptx

Carboxylate-Assisted Transition-Metal- Catalyzed C-H Bond Functionalizations: Mechanism and Scope;New words and phrases：;New words and phrases：;1. Introduction 2. Stoichiometric C-H Bond Metalation 2.1. Intermolecular Metalation 2.2. Stoichiometric Cyclometalations 2.3. Related Assisted Metalations with Monodentate Bases 3. Catalytic C-H Bond Functionalizations 3.1. Key Observations with Stoichiometric Amounts of Carboxylates 3.1.1. Aryl Halides as Arylating Reagents 3.1.2. Dehydrogenative Arylations 3.2. Catalytic Amou