第5章-气固界面-2异相催化分解.pptVIP

BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * BEA Confidential * 催化材料较强的单位 BEA Confidential. | * 催化材料综合举例1 催化材料综合举例2 滞后圈 比表面积 催化材料综合举例3 比表面积 吸附等温线 作业：查找一篇文献 基础分：和吸附等温线、反应机理、催化都相关 60分 附加分： 指出吸附等温线类型 10分 指出反应类型 10分 指出催化的作用（选择性、高效…） 10分 找出一篇文献的作者所在单位、情况和单位地理位置。 英文论文 10分 BEA Confidential. | * BEA Confidential * BEA Confidential * 8.11 Heterogeneous catalysis (异相催化) In heterogeneous catalysis the catalyst is in a different phase from the reactants, in contrast with homogeneous catalysis where the catalyst and the reactants are in the same phase. 异相催化中，催化剂和反应物在不同的相；而均相催化中催化剂和反应物在同一相中。 8.11 Heterogeneous catalysis (异相催化) Thus, heterogeneous catalysis usually involves the presence of a solid catalyst to increase the rate of a reaction in solution or in the gas phase. 异相催化包含固体催化剂，它可以提高溶液或者气相中的反应的反应速率。 8.11 Heterogeneous catalysis (异相催化) Types of catalysis Homogeneous catalysis 均相催化 Process Products Catalyst Hydrolysis of an ester. Acid and Alcohol H+ 酯的水解 2. Oxidation of SO2 to SO3 SO3 NO in lead chamber process Heterogeneous catalysis 异相催化 Process Products Catalyst 1. Ammonia synthesis NH3 Fe with Al2O3 2. Methanol synthesis MeOH ZnO/Cr2O3 8.11 Heterogeneous catalysis (异相催化) Briefly, a catalyst is a substrate that: 1 increase the rate of a chemical reaction; 2 does not itself take part in the overall chemical reaction; 3 is unchanged chemically at the end of the reaction and the amount present is