Solutions to Exercises-Chapter 12-配位化学基础.docVIP

Solutions to Excercises Chapter 12 配位化合物基础 Ⅰ. ?Fill in the blanks 1. The name of [Cr H2O en C2O4 OH ] is ; the coordination sphere is ; its oxidation state of Cr is ; its coordination number is . hydroxooxalatoaqua ethylenediamine chromium III ; [Cr H2O en C2O4 OH ]; +3; 6 2. The observed magnetic moment of [Ni NH3 6]2+ is 3.2 BM. The hybridization of the complex is . The complex is known as orbital complex and the expected geometry is . sp3d2; outer-; octahedral 3. The formation constant, Kf is 2.1?013 for [Cu NH3 4]t2＋ and 2.9×109 for [Zn NH3 4]2＋. The reaction, [Cu NH3 4]2＋＋Zn