先驱体转化法制备氧化锆毡--ZrO2多孔复合材料的力学与热导率性能 -.docx

The thermal conductivity and mechanical properties of highly porous zirconia felt/ZrO2 composites by zirconium oxide precursor impregnationJianping Ai a,b, Guohong Zhou a,*, Zhengjuan Wang a,b, Hailong Zhang a, Xianpeng Qin a,b, Peng Liu a,Shiwei Wang a,*a The State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, Chinese Academy of Sciences, 1295 Dingxi Road, Shanghai 200050, PR Chinab University of Chinese Academy of Sciences, Beijing 100049, PR ChinaAbstract The vacuum pressure impregnation method was adopted to make both low thermal conductivity and high-temperature resistance porous zirconia felt/ZrO2 composites. Incorporating zirconia felt into porous zirconia matrix to improve the mechanical strength. Meanwhile, lanthanum nitrate as an additive to yttrium-stabilized zirconia to reduce the thermal conductivity of the matrix. The effect of sintering temperature on compressive strength and thermal conductivity were investigated on the basis of porosity, microstructure and composition. The tetragonal phase and the cubic phase co-existed at 1450℃, while the cubic phase predominated upon 1450℃ as zirconia ions were replaced by lanthanum and yttrium ions. And the open porosity and size of small pores decreased as the sintering temperature increased from 1450 to 1600℃ due to the zirconia grains grew up , a decrease of open porosity from 48.1% to 42.5%. Compared with other temperature sintered samples, the 1600℃-sintered samples always owned higher thermal conductivity value of 0.70~0.78 W/(m ?K) at lower temperature, inversely, possessed lower thermal conductivity after 800℃.IntroductionZirconia-based ceramics have high melting point, excellent mechanical strength, low thermal conductivity compared with other ceramics [1-3]. It is therefore of interest to consider them as thermal protections. Zirconia-based ceramics show promise as thermal barrier coatings (TBCs) [4-6]. TBCs offer advantage in thermal insulat