Electroanalytical – Voltammetric Methods Ch 23, 7 th e, WMDS).pptVIP

Electroanalytical – Voltammetric MethodsCh 23, 7th e, WMDS) Hmwk – Chapter 23 – due Monday, May 1 Problems 1, 5, 6 Electroanalytical – Voltammetric MethodsCh 23, 7th e, WMDS) Voltammetry is the name given to a wide range of methods that study the composition of a solution by looking at current – potential relationships. The variety of techniques are shown in Table 23.1, p 697. Electroanalytical – Voltammetric MethodsCh 23, 7th e, WMDS) Electroanalytical – Voltammetric MethodsCh 23, 7th e, WMDS) Electroanalytical – Voltammetric MethodsCh 23, 7th e, WMDS) Electroanalytical – Voltammetric MethodsCh 23, 7th e, WMDS) Electroanalytical – Voltammetric MethodsCh 23, 7th e, WMDS) Electroanalytical – Voltammetric MethodsCh 23, 7th e, WMDS) Electroanalytical – Voltammetric MethodsCh 23, 7th e, WMDS) Electroanalytical – Voltammetric MethodsCh 23, 7th e, WMDS) Electroanalytical – Voltammetric MethodsCh 23, 7th e, WMDS) Electroanalytical – Voltammetric MethodsCh 23, 7th e, WMDS) Electroanalytical – Voltammetric MethodsCh 23, 7th e, WMDS) Electroanalytical – Voltammetric MethodsCh 23, 7th e, WMDS) Electroanalytical – Voltammetric MethodsCh 23, 7th e, WMDS) Electroanalytical – Voltammetric MethodsCh 23, 7th e, WMDS) * Polarography (one of several voltammetric methods) is the measurement of current in an electrolysis cell as a function of the potential applied to the working electrode. (The name comes from the fact that the method biases the electrode, ie, puts an electrical charge on it.) This is not classified as an electrolysis method because only a few small amount of the sample is electrolyzed. The basis of this method is the diffusion current which is related to the concentration of the analyte. Important terms polarogram residual current limiting current diffusion current, Id polarographic wave supporting electrolyte half-wave potential - related to E1/2 for that half-cell r