分析锅炉石灰煅烧和盐化放热对循环流化的影响.docVIP

　分析锅炉石灰煅烧和盐化放热对循环流化的影响 添加石灰石脱硫的热化学反应包括caco3煅烧的吸热反应和硫酸盐化反应的放热反应两部分,其热化学反应方程式如下: Adding limestone desulphurization thermal chemical reactions including caco3 calcination endothermic reaction and the sulfuric acid salinization of the exothermic reaction of two parts, the thermal chemical reaction equations are as follows: 　　caco3——→cao+co2-1830kj/kgcaco3 Caco3 - - - 1830 kj/kgcaco3 cao + co2 　　cao+so2+1/2o2——→caso4+15141 kj/kgs Cao + so2 + o2-1/2 - caso4 + 15141 kj/KGS 　　一开始石灰石从给煤机绞龙添加进入炉膛后,床温均明显降低,这是因为石灰石进入炉膛后在高温下首先发生煅烧分解反应,这个反应是吸热过程,同时由于石灰石与燃煤混合后进入炉膛,在螺旋给煤机转速不变时,加石灰石后入炉煤量肯定减少了,放热量也减少,这两方面因素必然导致床温降低,而且加入的石灰石越多,即ca/s越高,床温下降越大也越快,当ca/s:2.5时,10分钟内床温由1000℃下降到980℃,降幅达20℃。然后温度回升至990℃,由于石灰石分解成氧化钙后与二氧化硫进行的硫酸盐化反应是放热过程,加上一部分氧化钙粒子经旋风分离器分离下来重新回到炉床上继续硫酸盐化的放热反应,使床温升高。每小时加入的石灰石量变成cao需要吸收的热量为670695kj,按照脱硫效率为80%进行 计算 硫酸盐化反应的放热量为528505kj,损失热量为142190kj。 Started from coal feeder ground limestone dragon enters the furnace to add, after the bed temperature were significantly lower, this is because the limestone into the furnace calcined at high temperature first, before and after the decomposition reaction, the reaction is endothermic process, due to limestone mixes with coal into the furnace at the same time, the spiral coal feeder at constant speed, after adding limestone into the coal must be reduced, and heat quantity is reduced, the two factors inevitably results in the decrease of bed temperature, and join the limestone, the more the ca/s is higher, the larger the bed temperature drop is the fast, when the ca/s: 2.5, 10 minutes bed temperature dropped from 1000 ℃ to 1000 ℃, a drop of about 20 ℃. Then back up to a temperature of 990 ℃, due to limestone is decomposed into calcium oxide and sulfur dioxide after sulphating reaction is exothermic process, through cyclone separator separation part combined with calcium oxide particles down to return to continue the sulfuric acid salinization exothermic reaction furnace bed, the bed temperature is high. Join the amount of limestone into