杜康毕业论文终稿.doc

攀枝花学院本科毕业设计（论文） 钛白白段清洁化生产工艺技术研究 学生姓名： 杜康 学生学号： 200711101008 院（系）： 材料工程学院 年级专业： 2007级材料科学与工程 指导教师： 邹建新 教授 助理指导教师： 二〇一一年六月  摘要 硫酸法钛白的生产工艺是采用钛渣酸解后获得硫酸氧钛，经水解后得到偏钛酸，再通过高温煅烧获得粉末，对于金红石型钛白产品，则需对该粉末进行后处理（包膜）才能得到商品钛白。在金红石钛白后处理过程中，需要对干粉状的钛白粗品加水使之变成液态状的浆料，经过砂磨机湿磨后包膜处理，再次干燥脱水并气流粉碎使之成为干粉状的钛白成品。 本实验采用新工艺，将包膜工序放在偏钛酸水洗及漂白工序后，直接对纯净的偏钛酸进行包膜处理，再经煅烧并气流粉碎后即可得商品钛白，并以煅烧温度、煅烧时间、包膜温度、包膜剂、包膜速度等变量作参数，做多组样品进行对比，并得出最优参数：煅烧温控在600℃(3h)-850℃(4h)-900℃(3h)、包膜温度85℃的硅铝包膜新工艺产品的蓝相光谱特征值、白度、吸油量最佳；煅烧温控在500℃(2h)-810℃(5h)-880℃(2.5h)、包膜温度45℃的锆铝包膜新工艺产品的消色力、色调（绝对值）、亮度、微观形貌、物相、晶型最佳。实验表明新工艺得到的钛白与传统工艺得到的钛白品质相当。 ABSTRACT The production process of titanium dioxide by sulfuric acid is to use the ulfuric acid solution to dissolve the titanium dioxide slag to get the liquid titanium, and get the metatitanic after partial hydrolysis ,and then get the powder after calcining with high temperature.You need to post-processing of the powder (envelope) to get the product titanium dioxide for the rutile titanium dioxide products.For obtaining the slurry of itanium dioxide,you should add some water into the crude dry powder of titanium dioxide in the rutile titanium dioxide in the post-processing. metatitanic should be coated after sanded by sander.Finally,you should make it drying and dehydration and smash it to get the titanium dioxide product which is dry powder. In this study,we will use new technology and processes which is that envelope will be coated after the washing and bleaching process of metatitanic ,and pure metatitanic will be directly to be coated, then we can get the titanium dioxide product after calcination and smashing. and we argue calcined temperature, calcination time, the capsule temperature, pH, coating time, coating amount, coating speed and other variables to get the best parameters.we also make some samples to compare to get the best parameters.when the calcination temperature at 600 ℃ (3h) -850 ℃ (4h)