二氧化碳光催化详解.docVIP

氟化石墨烯以及氟化高分子有机物自身的光催化作用 改性对于氟化碳结构的影响 A novel PdAu bimetallic catalyst with a PdAu@Au core?shell nanostructure supported on carbon was facilely synthesized by a simultaneous reduction method without using any stabilizer. The structure was characterized by cyclic voltammetry, X-ray diffraction, transmission electron microscopy (TEM), and high-angle annular dark-field scanning TEM combining with X-ray energy-dispersive spectroscopy. The obtained catalyst was applied in hydrogen generation（氢气发生器） from formic acid （有机酸）decomposition. Results show that the structured bimetallic catalyst possesses superior activity, high selectivity, and stability at low temperature. The reforming gas from formic acid decomposition contains only 30 ppm of CO and can be used directly in fuel cell. In this paper, a novel core?shell nanostructure of PdAu was prepared by a facile simultaneous reduction method without adding any stabilizing agent. It contains a core of PdAu alloy and an Au shell. More important, the PdAu bimetal system is supported on carbon and can be used directly as a heterogeneous catalyst without further treatment. The most remarkable finding is that the structured PdAu bimetallic catalyst shows superior activity, high selectivity, and stability in formic acid decomposition for hydrogen generation at low temperature. pdau新型核壳纳米结构对于氢气产生催化作用。高活性，高选择性，有机酸中稳定性以及低温下稳定性 二氧化钛，化学式为TiO2，俗称钛白粉，多用于光触媒、化妆品，能靠紫外线消毒及杀菌，现正广泛开发二氧化钛性质稳定，它具有良好的遮盖能力二氧化钛是一种N型半导体材料，锐钛矿相TiO2的禁带宽度Eg =3.2eV，由半导体的光吸收阈值λg与禁带宽度E g的关系式：λg (nm)=1240/Eg(eV) 可知：当波长为387nm的入射光照射到TiO2上时，价带中的电子就会发生跃迁，形成电子-空穴对，光生电子具有较强的还原性，光生空穴具有较强的氧化性。在半导体悬浮水溶液中，半导体材料的费米能级会倾斜而在界面上形成一个空间电荷层即肖特基势垒，在这一势垒电场作用下，光生电子与空穴分离并迁移到粒子表面的不同位置，还原和氧化吸附在表面上的物质。除了上述变化途径外，光激发产生的电子、空穴也可能在半导体内部或表面复合，如果没有适当的电子、空穴俘获剂，储备的能量在几个毫秒内就会通过复合而消耗掉，而如果选用适当的俘获剂或表面空位来俘获电子或空穴，复合就会受到抑制，随后的氧化还原反应就会发生。在水溶液中，光生电子的俘获剂主要是吸附在半导体表面上的氧，氧俘获电子形成O2-；OH-、水分子及有机物本身均可充当光生空穴俘获剂，空穴则将吸附在TiO2表面的OH-和H2O氧化成具有高度活性的?OH自由基，活泼的?OH自由基可以将许多难以降解的有机物氧化为CO2和H2O。其反