高等有机化学-第六章不饱和碳碳键的加成反应资料.ppt

The stereochemistry of the Diels–Alder reaction * * (decyl)Me3 NMnO4 and Me3SiBr * 6-26 The Sakurai Reaction 6-27 Conjugate Addition of Boranes to Activated Double Bonds 6-28 Radical Addition to Activated Double Bonds 6-29 Radical Addition to Unactivated Double Bond 6-30 Radical Cyclization 6-32 Acylation of Activated Double Bonds and of Triple Bonds 6-33 Addition of Alcohols, Amines, Carboxylic Esters, Aldehydes, and so on. 6-34 Addition of Aldehydes Rhodiumcompounds or Yb(OTf)3 6-35 Hydrocarboxylation 100–350oC and 500–1000 atm 6-36 Carbonylation, Alkoxycarbonylation and Aminocarbonylation of Double and Triple Bonds CuCl2 and PdCl2 6-37 Hydroformylation 6-38 Addition of HCN CuCl, NH4Cl, and HCl；Ni or Pd compounds. Et2AlCN, HCN and R3Al 6-39 Halogenation of Double and Triple Bonds p-TolIF2/Et3N ·5 HF a mixture of PbO2 and SF4 Me3SiCl MnO2, NaClO2/Mn(acac) 2/moist Al2O3,BnNEt3MnO4/Me3SiCl, and KMnO4-oxalyl chloride. C5H5NHBr3 (decyl)Me3NMnO4 and Me3SiBr CuBr2 or CuCl2 BrCl ICl Br2 IBr I2 6-40 Addition of Hypohalous Acids and Hypohalites 6-41 Halolactonization and Halolactamization 6-42 Addition of Sulfur Compounds 6-43 Addition of Halogen and an Amino Group 6-44 Addition of NOX and NO2X 6-45 Addition of XN3 6-46 Addition of Alkyl Halides CCl4, BrCCl3, ICF3 6-47 Addition of Acyl Halides 6-48 Hydroxylation 6-49 Dihydroxylation of Aromatic Rings 6-50 Epoxidation 6-51 Hydroxysulfenylation 6-52 Oxyamination 6-53 Diamination 6-54 Formation of Aziridines 6-55 Aminosulfenylation 6-56 Acylacyloxylation and Acylamidation 6-57 The Conversion of Alkenes to g-Lactones 6-58 1,3-Dipolar Addition 6-60 The Diels–Alder Reaction 6-5 Addition of Alcohols and Phenols 6-6 Addition of Carboxylic Acids to Form Esters C. Sulfur on the Other Side 6-7 Addition of H2S and Thiols D. Nitrogen or Phosphorus on the Other Side 6-8 Addition of Ammonia and Amines, Phosphines, and Related Compounds Pd, Mo, Rh, La 6-9 Addition of Amides 6-10 Addition of Hydrazoic Acid TiCl4 E. Hydrogen on Both Sid