FundamentalsofSolidification.docVIP

Chapter 5 Fundamentals of Solidification 作业1：The solid-liquid interfacial energy of pure silver is 0.126J/m2. The latent heat of melting is 104.6J/g. The melting point of pure silver is 961℃. The density of solid/liquid silver at the melting point is 10.5g/cm3. 15points What is the value of the critical radius at 700℃? What is the value of ΔG* at this radius Solution: r* - 1.0848×10-7cm 作业2：This diagram is for a hypothetical embryo of silver growing against an arbitrary mold wall. With the aid of this diagram, Compute the angle of contact, θ, of the embryo with the mold wall. Determine the magnitude of the factor that may be used to convert the homogeneous free energy needed to obtain a nucleus into that of the corresponding heterogeneous free energy. Solution: （a） ℃ b 作业3: 已知纯铜的熔化潜热为1.88×109J/M2,熔点为1089℃，点阵常数为3.4167?, 发生均匀形核过冷度为230K，。求铜的临界晶核半径及临界晶核中所含的铜原子数。 解答： 晶胞体积，每个晶胞含4个Cu原子，晶核所含铜原子数个 作业4：已知锌的熔点为419℃，其结晶潜热为7×10J/m,液固界面能，锌的原子量为65.4，密度为7.18g/cm,试计算锌在350℃结晶后的临界晶核半径，并说明晶核内有多是个锌原子？ 解答： 晶核重量 晶核中含有原子数 个 1408个 作业5： 9-2 suppose that liquid nickel is undercooled until homogeneous nucleation occurs. Calculate a the critical radius of the nucleus required; and b the number of nickel atoms in the nucleus. Assume that the lattice parameter of the solid FCC nickel is 0.356 nm. Solution From Table 9-1: ΔT 480℃ Tm 1453℃ 1726 K ΔHf 2756J/cm3 σsl 255×10-7 J/cm2 r* 6.654×10-8 cm The lattice parameter for FCC nickel is a0 0.356nm 3.56×10-8 cm Vunit cell a0 3 3.56×10-8 3 45.12×10-24cm3 Vr* 1233×10-24 The number of unit cell in the critical nucleus is Since there are 4 atoms in each unit cell of FCC matals, the number of atoms in the critical nucleus must be: 4 atoms/cell 27.33cell/nucleus 109atoms/nucleus 作业6 ：9-4 Suppose that solid nickel was able to nucleate homogeneously with an undercooling of only 22℃. How many atoms would have to group together spontaneously for this to occur? Assume that the lattice parameter of the solid FCC nickel is 0.356 nm. Solu