第七章 原子结构元素周期表(.DOC).docVIP

第七章　原子结构和元素周期律 Chapter 7　The Atomic Structure and Periodic System of Elements 这一章中，我们介绍物质的微观结构──原子结构。化学工作者总是希望通过对本质的认识，来明元素相互化合的原理，把化学事实系统化，使化学成为可以理解的容易加以记忆的学科利用这些原理来预言具有新功能的化合物的诞生。例如利用等电子原理（the isoelectronic principle）合成新的化合物： In 1971, the following isoelectronic compounds were knownand MnCo(NO)3. The last member of this series, Cr(NO)4, was unknown. However, in 1972, several chemists had sufficient faith in the isoelectronic principle to photolyze a solution of Cr(CO)6 in the presence of NO ,and thus they prepared. For many years chemists was unsuccessfully tried to prepare the perbromat