丁苯橡胶的合成术与发展综述.doc

丁苯橡胶的合成与发展综述 戴 协1 （常州大学 材料科学与工程学院，常州213164） 摘要： 丁苯橡胶是一种广泛使用的橡胶产品。其主要分为乳液丁苯橡胶、溶液丁苯橡胶。A SUMMARY OF SBRS SYNTHESIS AND DEVELOPMENT DAI Xie College of Material Science and Engineering，hangzhou University，Changzhou 213164 ,China ABSTRACT: Styrene-butadiene rubber SBR is kind of the widely u-sed rubber products. SBR is the first rubber that human can synthesize by industrial production，and it also has the highest rate of production and consumption. As one of the most important rubber materials，it is divided into emulsion-polymerized styrene-butadiene rubber ESBR and solution-polymerized styrene-butadiene rubber SSBR . Firstly，This paper introduced the synthetic method of ESBR and SSBR and the performanc-e features of the two rubbers. Secondly，it summarized the development of the technology of SBRs synthesis and the situation of production andconsumption at home and abroad. Finally，it estimated the technology i-n the future and market prospect. KEYWORDS: styrene-butadiene rubber ; synthetic method ; production and consumption 1.引言 当今世界三大高分子材料是：塑料、纤维和橡胶。橡胶工业中丁苯橡胶（SBR 是最大的通用合成橡胶品种，也是合成橡胶中工业化最早、产耗量最大的胶种。它是丁二烯与苯乙 烯的无规共聚物。其物理机构性能，加工性能及制品的使用性能接近于天然橡胶，有些性能如耐磨、耐热、耐老化及硫化速度较天然橡胶更为优良　-甲基丙烯酸基氧三丙氧基硅烷单体单元和小于50%的苯乙烯单体单元组成的新型E-SBR和一种由大于45%的丁二烯单体单元、小于20%的-甲基丙烯酸基氧三丁氧基硅烷单体单元、小于20%的甲基丙烯酸羟乙酯单体单元和小于50%的苯乙烯单体单元组成的四元共聚E-SBR。在合成E-SBR时加入0.01%-5%（以丁二烯计）的丙烯参与共聚，可使单体转化率在6.1h时达到70%，产物门尼粘度[ML 1+4 100℃]为72，而无丙烯存在时, ML 1+4 100℃只有46[1]。 2.2.2 ESBR的性能特点与用途 常温下为白色固体或透明无悬浮物液体，有微芳香味，是一种性能上更优于工业直链烷基苯的洗涤剂产品原料。以其为原料衍生的表面活性剂产品，性能优良，生物降解性能好，耐硬水，皮肤感觉柔和，脱脂力小，更适合低温洗涤，在低温仍有卓越的去污能力。SBR－1500是通用污染型软丁苯橡胶的最典型品种，生胶的粘着性和加工性能均优，硫化胶的耐磨性能、拉伸强度、撕裂强度和耐老化性能较好。SBR-1500广泛用于以炭黑为补强剂和对颜色要求不高的产品，如轮胎胎面、翻胎胎面、输送带、胶管、模制品和压出制品等。 customer qualification preliminary examination of the material of the borrower for the loan person, determine whether you meet the loan conditions standard specification for details of the conditions the fifth chapter 5.1 loans and borrower conditions . 3. agree loan person decides to accept, according to