《Ba取代对双钙钛矿型Sr2CaMoO6Eu3+荧光粉结构及发光性能的影响》.docVIP

Ba取代对双钙钛矿型Sr2CaMoO6:Eu3+荧光粉结构及发光性能的影响 摘 要：本文采用EDTA-柠檬酸联合络合法成功制备了一系列A位Eu3+掺杂的Sr2CaMoO6:Eu3+荧光粉，主要研究了Ba部分取代对荧光粉结构和光谱性能的影响。结果表明：Sr2CaMoO6:Eu3+荧光粉强的电荷迁移吸收带位于200-450 nm，与LED蓝光荧光粉发射波长几乎不存在重叠；该荧光粉可同时被近紫外光和蓝光激发，在400 nm的电荷迁移带激发下，A位Eu3+具有更强的红光发射。随着Ba取代量的增加，样品的晶胞参数增大，同时伴随着样品结构由单斜P21/n向x立方Fm3m转变，在相同的结构下，Ba的增加将降低了Eu的发光强度，但x≥ 0.8后，部分Eu3+进入B位，荧光粉发光强度提高。 关键词：特种功能无机非金属材料；白光LED；EDTA-柠檬酸联合络合法；双钙钛矿；红色荧光粉 Crystal structures and luminescence properties of double- perovskite Sr2CaMoO6:Eu3+ phosphor substituted by Ba Abstract： Series of A site Eu3+doped Sr2CaMoO6:Eu3+ phosphors were successfully synthesized by EDTA-citric acid complex method, and their crystal structures and luminescence properties substituted by Ba were investigated in detail, respectively. The results showed that: the strong charge transfer band of Sr2CaMoO6:Eu3+ phosphor lay in 200-450 nm, which was not overlap with the emission spectrum of blue phosphors. This phosphor could be excited by NU and blue light. A site doped Eu3+ had stronger red emission when excited by 400 nm of charge transfer band. With increasing the amounts of Ba, the lattice parameters of the samples increased, and their space group turned from monoclinic P21/n to cubic Fm3m. In the same structure, the increasing amount of Ba would decrease the intensity of Eu, but its intensity enhanced due to part of Eu3+ into B sites, when x≥ 0.8. Key words：inorganic nonmetallic materials; white LED; EDTA-citric acid complex method; double- perovskite; red phosphors 引言 白光LED作为新型光源，具有寿命长，响应速度快，色彩丰富饱满，可做全彩变化，无紫外线，低压安全等特点[1]，高功率LED的问世更是大大扩大了LED的使用范围，使其在汽车，指示灯，手机背光灯等领域获得初步应用。白光LED发光方式主要有近紫外光芯片激发红、绿、蓝三基色荧光粉获得白光，或蓝光芯片激发红、绿荧光粉，然而红光荧光粉对比蓝粉和绿粉存在工作寿命短不稳定效率低，限制了白光LED的发展。因此开发能够被近紫外光和蓝光有效激发的红色荧光粉成为白光L ED 应用的一个关键步骤. 目前使用的红粉主要有(Ca1-xSrx)S:Eu2+体系，在蓝区激发，红区发射:激发与发射谱都很宽，:共掺杂Er3+，Te3+，Ce3+等可增强红光发射[，]。然而，该体系硫化物基荧光材料在近紫外光照射下，化学稳定性欠佳，使用寿命不足[-5];Y2O2S: Eu 体系红色荧光粉，其缺点是色纯度和发光效率仍不十分理想CaS:Eu2+、Y2O3:Eu3+等的发光强度远低于同激发的蓝色与绿色荧光粉[]。因此，在近紫外到蓝光范围内具有高效吸收的红色荧光粉获得了广泛研究，如钨钼酸盐、磷酸盐、钒酸盐、钛酸盐等[