20116650-李洪江-羧酸配体的设计与组装分析报告.doc

重庆大学本科学生毕业设计（论文） 基于羧酸配体的金属有机配合物设计与组装 学 生：李洪江 学 号指导教师：龚云 专 业：应用化学 重庆大学化学化工学院 二O一五年六月 Graduation Design(Thesis) of Chongqing University Design and assembly of metal organic complexes based on carboxylic ligand Undergraduate: Li Hongjiang Supervisor: Prof. Gong Yun Major: Applied Chemistry Chemistry and Chemical Engineering Chongqing University June 2015  中文摘要 金属有机骨架（s）是以金属离子作为连接点，以有机配体构成，在储能、催化以及分离等方面都起到了广泛的作用分子识别、选择催化、超高纯度分离、光致变色、生物传导、光电材料。由于金属有机骨架材料（MOFs）具有结晶度高、纯度高、成本低结构可控等一系列优点，它近些年来受到了全世界材料学研究的广泛关注。 本文采用水热法，利用4-氧基1-吡啶与采用水热法合成两种金属-有机骨架配合物：CdL(H2O)21)和CdL (2)，并对配合物1和2的结构进行了单晶X射线衍射表征。在配合物1和2中，配体L2-采用不同的配位方式，但是这两个配合物都是二维层状结构。粉末X射线衍射配合物是纯相样品。紫外可见光谱。 关键词：金属有机骨架，水热合成，含氮羧酸，晶体结构  ABSTRACT Metal-organic frameworks (MOFs) possess infinite extensive network in which metal ions or metal cluster act as nodes and organic ligands function as linkers, they play important roles in storing energy, catalyzing and separation and they may have potential applications in molecular recognition, selective catalysis, separation with ultra-high purity, photochromism, biology conduction and photoelectric field. Because MOFs have a serial of advantages such as high crystallinity, high purity, low cost and adjustable structures, they have drawn extensive attention by the researchers all over the world. In this paper, using 4-(4-oxypyridinium-1-yl)phthalic acid (H2L) and Cd2+, two MOFs formulated as CdL(H2O)2 (1) and CdL (2) have been synthesized hydrothermally. The two MOFs have been structurally characterized by single crystal X-ray diffraction. In complexes 1 and 2, L2- ligand adopts different coordination modes, but the two complexes are two dimensional (2D) layer structures. Powder X-ray diffraction data indicates the bulk sample of complex 1 is in pure phase. The UV-vis spectrum and thermally stability of complex 1 have also been measured. Key words：MOFs, hydrothermal synthesis, Carboxylic ligand containing N atom, crystal stru