柴油功率超聲氧化-萃取脱硫技术的研究.docVIP

柴油功率超声氧化－萃取脱硫技术的研究 董丽旭 （石油化工学院 化学工程与工艺专业0204） 摘要：本实验研究了超声作用下柴油氧化脱硫，采用H2O2作为此工艺的氧化剂。通过对不同浓度的H2O2对河南南阳催化裂化柴油脱硫效果考察发现，30%浓度的H2O2的脱硫率最高。同时无机酸催化剂的脱硫效果表明，硫酸和磷酸按1:1比例混合效果最好。再加入金属催化剂后脱硫率更高。 实验结果表明了，功率超声作用下，H2O2—硫酸与磷酸1/1混合酸体系的最优操作条件：氧化体系:油(体积比)＝3:10；H2O2:混合酸（体积比）=1:1；超声作用时间9min。萃取剂:DMF；萃取剂：油（体积比）=1:1；萃取一次。硫含量从1936.48μg/g降到99.73μg/g，脱硫率94.8%，油收率90.2%。可见功率超声强化了整个氧化脱硫过程。此外，在相同的氧化和萃取条件下，柴油在低频 28kHz 时的脱硫效果比 40kHz 的脱硫效果好；同时在功率超声的功率为200W时脱硫率最大。 关键词: 柴油；脱硫；氧化；萃取；功率超声 The Research on Deep Oxidative Desulfurization－Diesel via Ultrasound BSTRACT： oxidation desulfurization in diesel was widely researched via ultrasound irradiation in the experiment. We use H2O2 as this experiment’s oxidation agent. The desulfurization result of various concentration H2O2 showed that the sulfur removal rate of 30% H2O2 was the most effective. At the same time in the experiment , some inorganic acid showed that the sulfur removal rate is best when sulfuric acid and phosphoric acid mixing at one to one. The desulfidation rate more higher when add to the metal catalyst. The result of the experiment indicates that with ultrasound irradiation, the optimal operating conditions of H2O2－mixing acid system in the laboratory is the quantity of the oxidative reagent : oil is 3:100(the volume ratio); the volume ratio of oxidative reagent and mixing acid is 1:1; reaction time is 9min; extraction sovent is DMF; the volume ratio of extraction sovent and oil is 1:1; extraction one time. The amount of sulfur content can lower from 1936.48μg/g to 99.73μg/g, the desulfuridation rate is 94.8%, the oil recover rate is 90.2%. The ultrasound can intensify the oxidative process. Furthermore, in the same oxidative and extraction condition, the desulfurization result of low frequency 28 kHz is better than 40 kHz. It is also been found that the sulfur removal rate reach to the most high when power is 200W. Key words: Diesel; Desulfurization; Oxidation; Extraction; Ultrasound 近年来，世界各国对运输燃料的需求量显著增长，由燃油造成的总排放量也不断增加。为了减少汽柴油发动机的排放，