CoO改性TiO_2光催化从水析氢光电化学行为研究.docxVIP

2005 年第 63 卷化 学 学 报Vol. 63, 2005第 8 期, 671～676ACTA CHIMICA SINICANo. 8, 671～676·研究论文·CoO 改性 TiO2 光催化从水析氢光电化学行为研究吴玉琪吕功煊*李树本(中国科学院兰州化学物理研究所羰基合成与选择氧化国家重点实验室兰州 730000)摘要 评价了不同 Co 担载量的 CoO-TiO2 系列光催化剂在无氧条件下光催化重整乙醇水溶液反应中析氢性能, 并利用 连续瞬间电流-时间响应和循环伏安法等电化学方法, 重点考察了不同 Co 担载量光催化剂在紫外和可见光光照条件下 电流响应强度和起始响应速率的差别, 以及暗态和光照条件下光催化析氢电位变化等光电化学行为. 实验结果表明, 适当量 CoO 的改性能够显著地提高 TiO2 光催化析氢性能, 表现出了良好的稳定性, 最佳担载量为 0.4% Co, 将产氢速 率由原来的2.9×10－3 mL?h－1 提高到了2.85×10－1 mL?h－1, 提高了近2 个数量级. 光电化学行为研究表明, 紫外光照射 时CoO 改性明显增强了TiO2 的光电流响应强度, 其相对大小顺序为: 3.0% Co＞0.4% Co＞0.0% Co, 但光电流起始响应 速度随着担载量的增加有所下降, 其相对大小顺序是: 0.0% Co≈0.4% Co＞3.0% Co. 利用可见光源照射时, 除光电流 响应强度总体下降, 光电流响应强度的相对大小顺序为 0.4% Co＞0.0% Co＞3.0% Co, 而光电流起始响应速度十分接 近.关键词 光催化; 光电化学; CoO-TiO2; 制氢Photoelectrochemical Performance of CoO-loaded TiO2Photocatalysts for Hydrogen Generation from WaterWU, Yu-QiLü, Gong-Xuan*LI, Shu-Ben(State Key Laboratory for Oxo Synthesis and Selective Oxidation, Lanzhou Institute of Chemical Physics, Chinese Academy of Sciences, Lanzhou 730000)Abstract This paper reports the investigations on the preparation and hydrogen-evolving performance of CoO modified-TiO2 photocatalysts, and the photoelectrochemical performance with the methods of succes-sive sudden photocurrent-time and cyclic voltammetry. The differences between CoO modified and pure TiO2 photocatalysts on intensity of photocurrent response, starting-response speed and hydrogen-evolving photopotential were discussed in detail. The results showed that an appropriate amount of CoO loading could obviously enhance the hydrogen generation rate from water with a satisfied stability during experi-mental period. And the optimum loading content of Co was 0.4%. The hydrogen-evolving rate increased from 2.9×10－3 mL?h－1 of pure TiO2 to 2.85×10－1 mL?h－1 of CoO-TiO2 photocatalyst with 0.4% Co con-tent (ca. two order of magnitude). The results of the photoelectrochemical performance under a UV light il-luminating condition showed that the CoO modification on the TiO2 photocatalyst enhanced the