胺基功能化石墨烯的制備及对染料的吸附性能.docVIP

PAGE 1 胺基功能化石墨烯的制备及对染料的吸附性能 摘　要 【摘要】功能化石墨烯材料能快速对目标分子进行吸附分离，有效的用于在较短的时间内处理大量的废水，并且具有低毒、价格低廉、对生态环境友好等特点。本文合成了功能化石墨烯纳米材料(G- ethylenediamine)，并以此作为吸附剂，建立了分散固相萃取环境水样中的甲基橙（MO）的新方法。通过紫外光谱（UV）、XRD、红外光谱(FT-IR)对吸附剂进行表征。考察了功能化石墨烯用量、吸附时间、pH、盐类等对吸附性能的影响。结果表明，在5.0mg G- ethylenediamine纳米材料中，吸附时间为60min，pH为2.0的溶液中，甲基橙的吸附率达到最高88.2%。甲醇可有效洗脱吸附在G- ethylenediamine纳米材料表面的甲基橙，回收后的吸附剂可再利用。 【关键词】功能化石墨烯纳米材料；染料；甲基橙；吸附；洗脱 中图分类号： Abstract 【ABSTRACT】 Functionalized graphene material can quickly absorb and separate target molecule, and it was used to handle the large amount of wastewater in a shorter period of time, and has low toxicity, low cost, eco-friendly features. Functionalized graphene nanomaterials (G- ethylenediamine) was synthesized and used as an adsorbent for the dispersive solid-phase extraction of HYPERLINK app:ds:methyl \t methyl HYPERLINK app:ds:orange \t orange (MO) from environmental water. UV, FT-IR and X-ray diffraction were used to investigate the chemical structure of G- ethylenediamine nanocomposite. The effects of pH, adsorption, pH time and added salt on the adsorption of MO were examined, respectively. Results showed that the quality of G- ethylenediamine is 5.0mg, the balance adsorption time is 60 min, in an aqueous phase of pH 2.0, the highest adsorption efficiency achieved 88.2%. Absolute HYPERLINK app:ds:methyl \t methyl HYPERLINK app:ds:alcohol \t alcohol was effective in eluting MO on the G- ethylenediamine and can realize the recycling of adsorbent. The G- ethylenediamine adsorpt MO followed Langmuir adsorption isotherm with a maximum adsorption capacity of 79.6 mg/g and a Langmuir adsorption equilibrium constant of 5.39mL/μg . 【KEYWORDS】G-ethylenediamine nanocomposite; Synthesis; Diethylstilbestrol; Adsorption; Elution 1.绪论 1.1石墨烯及功能化石墨烯结构和特点 1.1.1石墨烯的结构和特点 石墨烯，一种新型的单原子厚的两维石墨碳系统，是材料科学的地平线上冉冉升起的新星。由于迷人的机械，电气，热和光学性质和潜在的在纳米电子学，传感器，催化，电池和超级电容器和晶体管的应用，近年来石墨已收到密集关注。比较碳碳纳米管（CNTs），石墨具有完善的sp2杂化的碳纳米结构和较高的比表面积，可很容易通过一个简单的天然石墨氧化，以较低的成本过程获得。此外，通过化学氧化法的修改，使富含有氧功能团出现在石