第六章 表界面a化学反应与材料的制备-杂化材料与自组装.pptVIP

有机硅烷SAMs在基底表面的自组装过程示意 翟怡、张金利等，化学进展，2004，16（4）：477－484 自组装单分子膜的主要体系 ■有机硅烷/SiO2（或Al2O3、玻璃、石英、 硅、云母、GeO2、ZnSe） ■烷基硫醇/金（或银、铜） ■二羟基硫化物（RSR/)（或二羟基二硫化物（RS-SR/)）/金 ■醇（或胺）/铂 ■羧酸/ Al2O3（或CuO、AgO） 超晶格层状结构 phage 抗菌素 缩氨酸 层状超晶格结构 Characterization of the liquid crystalline suspensions of A7 phage–ZnS nanocrystals (A7-ZnS) and cast film. AFM micrograph of a cast film from an A7-ZnS suspension (30 mg/ml) showing close-packed structures of the A7 phage particles. 纳米线或者纳米管 Ultrathin Single-Crystalline Silver Nanowire Arrays Formed in an Ambient Solution Phase Fig. 2. Organic nanotube templates and a silver nanowire inside the nanotube. (A) A schematic view of CHQ nanotube arrays based on the x-ray analysis of the crystal (orthorhombic, space group Cmmm with lattice constants: a 5 2.50 nm, b 5 2.33 nm, c51.16 nm and a 5 b 5 g 5 90°) reveals that the pores of 0.6 3 0.6 nm2 (with van der Waals volume excluded) are separated by 1.7 nm from the neighboring ones. Water molecules are not shown for clarity.atoms are shown in red. (B) CHQ monomer. (C and D) Top and side views, respectively, of a silver nanowire inside a CHQ nanotubetemplate. The solvent-accessible surface model in (C) and the stick model in（D） Fig. 2. HREM images and EDS elemental analysis of the nanowires. (A)Low-magnification image of the silver nanowires formed in CHQ nanotube templates (scale bar, 100 nm). (B) EDS elemental analysis indicating that the only metal present is silver. La1 and Lb1 are the transitions responsible for the x-ray fluorescence lines of silver. (C) Magnified image of (A) showing that 1D structures are unidirectional and monodispersed (scale bar, 2 nm). (D) Magnified image of (C) at atomic resolution showing coherent orientations of silver atoms in different wires. The white arrow indicates the wire direction, [110] (scale bar, 1 nm). (E) Image of the nanowire arrays piled over each other (scale bar, 5 nm). Fig. 4 Structural analysis of the single-crystalline primitive silver nanowire arrays