Na2CO3-NaCl-C-PbSO4-CuO体系热力学分析及应用研究.docVIP

Na2CO3-NaCl-C-PbSO4-CuO体系热力学分析及应用研究 曾萍，唐朝波，唐雷，李云，刘永 中南大学 冶金与环境学院，长沙 410083 摘要：对Na2CO3-NaCl-C-PbSO4-CuO低温熔盐炼铅体系进行热力学分析，绘制了600~1 200 K体系中主要反应的△GθT—T图。结果表明，在600~1 200 K范围内，PbSO4可以被还原成金属Pb，硫能够固定在CuS中，钠盐可转变成Na2CO3形态存在，且在1 123 K时，体系中的稳定物相以金属Pb、CuS和Na2CO3为主。提出了Na2CO3-NaCl-C-PbSO4-CuO低温熔盐炼铅新工艺在1 153 K下，以废铅酸蓄电池胶泥为原料、Na2CO3-NaCl为熔剂、CuO为固硫剂、焦粉为还原剂，进行了验证试验。产出的粗铅品位98.10%，铅直收率93.27%，铅的总回收率99.25%，93.81%的以CuS形式被固定在渣中，过程无SO2气体产生，与热力学分析结果相符合。 关键词：低温冶金；再生铅；热力学分析TF812 文献标志码：A 文章编号：1007-7545（2016）12-0000-00 Thermodynamic Analysis and Application of Na2CO3-NaCl-C-PbSO4-CuO System ZENG Ping, TANG Chao-bo, TANG Lei, LI Yun, LIU Yong (School of Metallurgy and Environmental, Central South University, Changsha 410083, China) Abstract：Thermodynamic analysis of Na2CO3-NaCl-C-PbSO4-CuO low temperature alkaline system for lead smelting was carried out. Curves between △GθT and reaction temperature (T) of different reactions at 600~1 200 K were obtained based on calculation. The results show that PbSO4 can be reduced to metal lead, sulfur can be fixed in CuS, and sodium salt can be converted into Na2CO3 at 600~1 200 K. The stable phases of the system are mainly composed of metal lead, CuS and Na2CO3 at 1 123 K. New process to smelt lead in Na2CO3-NaCl-C-PbSO4-CuO low temperature molten salt was proposed. Verification test was carried out at 1 123 K applying spent lead-acid battery colloid sludge as material, Na2CO3-NaCl as flux, CuO as sulfur additives, and coke powder as reducing agent. Grade of crude lead is 98.10% with lead direct yield of 93.27% and lead total yield of 99.25%. 93.81% of sulfur embraced in raw materials can be fixed as CuS without SO2 emission through whole process. The verification test results are in accordance with thermodynamic analysis results. Key words：metallurgy at low temperature; secondary lead; thermodynamic analysis 我国铅资源具有富矿少、贫矿多、单一矿少的特点，再生铅的生产能缓解铅矿资源短缺、促进资源综合利用。而我国传统的再生铅企业存在的突出问题是综合利用率低、能耗高、环境污染严重。本文提出了一种熔炼温度低、环境友好、过程简单的低温熔盐炼铅新工艺废旧铅蓄电池胶泥，解决了传统炼铅过程SO2浓度低的难题可以最大限