高性能DMC的制备(6.8)研究.docVIP

高性能 BMC的制备 摘 要 BMC (Bulk Moulding Compounds)称为团状模塑料预混料，是一种以热固性树脂作为基体的纤维增强复合材料。其中最常用的增强材料是玻璃纤维短切纱。玻璃纤维增强效果的好坏，与其在BMC模塑料及制品中的长度、分散状态及其与树脂界面的结合情况等等有关。针对杭申电气杭州红申电器有限公司BMC在制备制品时出现的强度不能满足部分开关用制品需求和制品固化速率慢等问题，本研究分析了不同型号玻璃纤维在不同的搅拌时间下BMC制品的强度，并探讨了固化温度及引发剂种类和配比对BMC制品成型速率、表观质量及制品强度的影响。 研究发现BMC搅拌时间过长或过短都会降低BMC制品的强度。这是因为搅拌时间过长，玻璃纤维折断量会很大，不利于增强BMC；BMC搅拌时间过短，玻璃纤维不能完全浸润，也不利于增强BMC。使用集束性好、含油率高的240型玻璃纤维，搅拌时间为4min时，玻璃纤维对BMC的增强效果最好。对固化温度和引发剂的探讨发现固化温度过低时，固化速率较慢；固化温度过高，则BMC制品表面会因苯乙烯挥发产生鼓泡现象。不改变引发剂的总量，以TBPB与TBPO的质量比为8:2代替原来的纯TBPB后，发现固化温度为160-170℃时BMC的固化速率最快。同时BMC制品的表观质量也很好，强度也有所提高。 关 键 词：BMC，玻璃纤维，机械性能，引发剂，固化温度，表观质量  PREPARATION OF HIGH PERFORMANCE BMC ABSTRACT BMC (Bulk Molding Compounds) is called bulk molding plastic premix, is a kind of fiber reinforced composites which use thermosetting resin as the matrix. The most common reinforcing material is chopped glass fiber yarn. Effect enhancement related to the length of glass fiber, its dispersion and binding to the resin in BMC and its products. Strength and forming rate prepared by BMC of Hangshen Electric Co., Ltd can not reach the requirements. In order to solve the problem, This study analyzed the strength of BMC products made by the different types of glass fibers under different stirring times. And discussed curing temperature, type and ratio of initiators effects on forming rate, apparent quality and strength. Found that it will reduce the strength of BMC products when time is too long or too short. It is because when mixing time is too long，it will be a large amount of broken glass fiber; when mixing time is too short, the glass fiber will not be completely infiltrated. The use of 240 glass fibers whose cluster and oil rate is good, the mixing time was 4min, the glass fiber reinforcement to the best of the BMC. Discussion on the curing temperature and initiator,we can fing that when the curing temperature is too low, the curing rate is slow; when the curing temperature is too high, the surface of BMC products will bubb