大学毕设论文---用于甲烷部分氧化的双层膜反应器.docVIP

SHANDONGＵＮＩＶＥＲＳＩＴＹ　ＯＦ　ＴＥＣＨＮＯＬＯＧＹ 毕业论文 用于甲烷部分氧化的双层膜反应器 学 院： 化学工程学院 专 业： 化学工程与工艺 学生姓名： 于 海 阔 学 号： 0812103212 指导教师： 杨 乃 涛 2012 年 6 月 摘 要 本实验首先用EDTA-柠檬酸盐法制得LSCN粉体，再通过相转化法制取LSCN前驱体，进而将前驱体烧制成双层致密透氧膜膜管，将制得的透氧膜管组装成LSCN的膜反应器进行甲烷部分氧化制合成气的反应。 本实验对制取的膜管进行气密性及机械性能进行测试合格后，组装成LSCN膜反应器来进行甲烷部分氧化制合成气进行研究，以Ni/γ-Al2O3为催化剂，研究反应器的的各项性能。 实验表明，制取的LSCN双层中空纤维膜管的气密性良好，机械性能良好，制作成POM反应器后，测试其透氧性能证明随着CH4扫气量的增加，透氧量增大，在同一CH4扫气量下，膜的透氧性能从增大逐渐改变成缩小。而CH4的转化率随着CH4扫气量的增加而增大，在4-6ml/min的扫气量时达到峰值，之后逐渐变小.。CO与H2的选择性均是随扫气量的增大而增大。相对，CO2的选择性，则是随之减小 关键词：甲烷部分氧化、LSCN，双层致密透氧膜，反应器 Abstract In this experiment, the first step is using EDTA-Citrate Method to make LSCN powder, then we prepare the LSCN precursor by phase inversion and thus burn it to double layer of dense membranes for oxygen separation membrane tubes. Assemble the obtained oxygen-permeable membrane tube into the LSCN membrane reactor for the partial oxidation of methane to syngas reaction. Take an exam on it for the air tightness and mechanical properties, when it had passed, assemble it into the LSCN membrane to study the partial oxidation of methane to syngas with Ni/γ-Al2O3 as the catalyst, then we take exams on the performance of it. The experiments show that the LSCN double-layer hollow fiber membrane tubes which we prepare before has a good performance on tightness and mechanical properties, with it, we made a POM reactor, the test on it shows that the oxygen content increase with the increasing of CH4 sweep gas, the oxygen permeability of the membrane changed from gradually increased into a narrow at the same time. The CH4 conversion rate increase with the increasing of CH4 sweep gas, and reached the peak in 4-6 min, then becomes gradually smaller. The select of CO and H2 increase with the increasing sweep gas, the relative selective of CO2 is decreasing. Keyword: POM, LSCN, double dense oxygen-permeable membrane, reactor. 目录 摘 要 I Abstract II 第一章 引 言 1 1.1甲