美国TA Rheology Application.PPT

Rheology and Application流变学、流变仪及其应用 研究材料的流动与变形 Non linear Flow Behavior非线性流动行为 Pseudo-plastic Elastic and viscous deformations弹性和粘性变形 弹性 粘性 时间依存性 Linear Non-linear Behavior线性和非线性行为 Linear flow regime 线性流动 Non linear behavior 非线性行为 Structure breaking 结构破坏 Non linear Flow Behavior非线性流动行为 Flow and viscometry流动与粘度计 Flow – Viscometry流动 － 粘度计 Single point measurement of the viscosity 粘度的单点测试 Typical Viscosity Values (Pa s)典型的粘度值 (Pa s) Multi-step flow – Viscometry多步流动 － 粘度法 Multi-point measurement of the viscosity. s(g) = flow curve h(g) = viscosity curve Types of Flow curves流动曲线的分类 Viscosity and flow curve models粘度和流动曲线模型 Thixotropic loop触变环 Shear ramp up and down or thixotropic loop The stress represents the instantaneous response to the applied rate. If the material is time dependent, the up and down curves are different Thixotropic loop触变环 Stress ramp in stress controlled mode应力扫描 Stress ramp The stress is increase from zero to a finite value and the deformation is measured as a function of time. An instantaneous viscosity can be calculated from the applied stress and the time derivative of the deformation Yield stress in a stress ramp屈服应力 The maximum viscosity method is more representative and reproducible then the strain tangent method Relaxation and oscillation松弛和动态振荡测试 Silicone putty test粘弹性材料测试 Relaxation time松弛时间 Dynamic Mechanical Analysis动态力学分析 Phase angle相位角 The measured shift between the input wave and the output wave is called Phase angle d The ratio between stress amplitude and strain amplitude is the Complex modulus G* Viscoelastic Parameters粘弹性参数 Dynamic Mechanical Behavior 动态力学行为 Non linear response非线性响应 Non linear behaviour非线性行为 Rheological Characterization流变性能表征 Summary 小结 Flow and viscometry Pseudoplastic; Thixotropic; Yield; Dilatant Relaxation time and oscillation Concept of the relaxation time Separation of energy storage and dissipation Mechanical spectroscopy Material time and Obs