结晶动力学和结晶热力学补充材料.ppt

徐军 地址：英士楼218 电话 手机Email：jun-xu@tsinghua.edu.cn Process of Polymer CrystallizationTwo steps: 1. Nucleation (成核) process Size DG 0 embryo super critic. size stable critical nucleus DG = Gcrystal – Gmelt , DG = DH – TDS Gcrystal = Gbulk + SAs DG = Gbulk - Gmelt + SAs =DGf + SAs A is the suface area and DGf is the bulk free energy change. a b c Schematic representation of the change in free energy as a function of size illustrating the nucleation process Types of crystal nuclei. (a) primary (初次), (b) secondary (二次), (c) tertiary (三次) nucleus. Ho