绝热卡计技术与应用解析.ppt

* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * ? 50? 五、应用于J公司制程 -VSP2 Test- Self-heat rate vs. temperature for thermal decomposition of various TBHP 15 mass% solutions. ? 51? 五、应用于J公司制程 -VSP2 Test- Adiabatic runaway detected by VSP2 ? 52? 五、应用于J公司制程 三、有机过氧化合物制程： DSC实验：(1)放热量 250J/g VSP实验：(1)放热量 250J/g (2)Organic peroxide (3)overflow小事故(轻微runaway) (4)credible worst case判定 (5)Vent sizing ? 53? 五、应用于J公司制程 三、有机过氧化合物制程： 制程安全设计： (1)batch改为semi-batch，依限制条件加ROOH(VSP确定为有限与可控制风险) (2)人因与管理 (3)减量控制 (4)紧急处理程序sop与紧急排放系统设计 ? 54? 六、DSC卡计技术之应用 紧急处理程序sop：1,2,4,5,6,7共六个步骤 ? 55? 感谢聆听 QA p.s.：安全设计或实验数据以观念表达或假设的相类似数据说明 * * * * * * * * * * * * * * * * * * * * * * * * * * ? 18? 三、绝热卡计之原理与测试 加速热卡计(ARC)特性： Oven weight约1 Kg,追热慢(self-heat rate 15K/min is reliable) Test bomb: Ti, s.s., HC alloy, Spherical shape, 10ml Without stirrer Thermal inertia(Φ) : 1-15 Sensitivity : self-heat as low as 0.02K/min Without the function of addition of another reactant or gas reactant (7) T = 25 to 500℃, P = 1 bar to about 100bar ? 19? 三、绝热卡计之原理与测试 排放测试热卡计(VSP)介绍(PHI-TEC类似)： Heat-wait-search and adiabatic + temperature ramp mode (for simulating fire case) Test bomb: Ti, s.s., HC alloy, can shape, 110ml With magnetic or mechanic stirrer Thermal inertia(Φ) : as low as 1.1 Sensitivity : self-heat as low as 0.05K/min Additional reagents or gases may be added (7)T = 25 to 500℃, pressure difference can be as large as 200 psi (8) Can be used for relief test in determining the two-phase flow (top venting or bottom dumping) ? 20? 三、绝热卡计之原理与测试 压力补偿加速热卡计(APTAC)介绍 Heat-wait-search and adiabatic + temperature ramp mode Test bomb: Ti, s.s., HC alloy, Spherical shape, 130ml With stirrer Thermal inertia(Φ) : as low as 1.1 Sensitivity : self-heat as low as 0.02K/min Additional reagents or gases may be added (7)T = 25 to 500℃, P = 1 bar to about 136bar ? 21? 三、绝热卡计之原理与测试 Dewar绝热卡