樹脂对铅(Ⅱ)的吸附行为研究东南.docVIP

110树脂对铅（Ⅱ）的吸附行为 蔡玲玲 王国华 周俊艳 陈双双 莫建军* （丽水学院化学与生命科学学院, 浙江丽水 323000） 摘要 研究了110树脂对铅的吸附行为，考查介质pH、温度、吸附时间等因素对吸附过程的影响。测得在HAc—NaAc 体系中pH=5.73时吸附最佳；静态饱和吸附容量为681.75mg?g-1，；表观吸附速率常数k298 =3.39×10-5 S-1 ；表观吸附活化能Ea =17.52kJ·mol-1；吸附服从Langmuir和Freundlich等温式；热力学参数△H=43.31KJ·mol-1，△G=-15.24 KJ·mol-1，△S=0.196KJ·mol-1·K-1；HCl和CdCl2使树脂的吸附量减少，而MgCl2和NaCl对吸附量基本没影响；并对负载树脂解吸进行探讨，用红外光谱方法讨论了吸附机理。 关键词 110树脂；铅（Ⅱ）；吸附；介质 The Adsorption Behavior of 110 Resin for Pb(Ⅱ) Mo Jianjun1 Shi Linmei2 Xiong Chunhua3 (1 College of Chemistry and Live Science,Lishui College, Lishui 323000, China; 2 Lishui Techonology college, Lishui 323000, China;3 Department of Chemistry,Zhejiang Gongshang University,Hangzhou 310035, China) Abstract：The adsorption behavior of 110 resin for Pb（Ⅱ）were inverstigated. And the influences of medium pH, temperature, retention time on adsorption process are studied . 110 resin has a good adsorptivity for Pb（Ⅱ） in HAc—NaAc medium at pH= 5.73 The statically saturated adsorption capacity is 681.75mg?g-1 at 298K. The apparent adsorption rate contant is k298 =3.39×10-5S-1.The apparent sorption activation energy of 110 resin for Pb（Ⅱ） is 17.52kJ·mol-1.The adsorption behavior of 110 resin for Pb（Ⅱ）obeys the Langmuir and Freundlich isotherm. The sorption thermodynamic parameters of 110 resin for Pb（Ⅱ） are enthalpy change △H=43.31KJ·mol-1, △G=-15.24KJ·mol-1,△S=0.196 KJ·mol-1·K-1. HCl and CdCl2 made the adsorption quantity of 110 resin acutely decrease, while MgCl2 and NaCl made the adsorption quantity of 110 resin almost had no influence.The desorption process of Pb（Ⅱ） from the pregnant resin is also researched. The sorption mechanism of 110 resin for Pb（Ⅱ）was confirmed by chemical analysis and IR spectrometry. Keyword ：110 resin;Pb(Ⅱ); sorption; medium 铅是引起环境污染的重要元素，因此对于如何富集、回收铅等问题，日显重要。有关含铅废水的处理已见报导，但存在吸附容量不大等缺点。近年来, 国内外高分子、分析化学家在新的高分子树脂的研制和分析特性测试、 贵金属回收及环境保护等方面的研究[1-9]比较活跃。而本工作是研究在HAc—NaAc体系中，110树脂吸附铅的性能和机理，该法的特点是吸附容量大，易再生等。因此可望成为一种铅废水处理及回收金属铅