ppt课件-hydrothermalbaxsr1-xtio3powdersformultilayercapacitors.pptVIP

Hydrothermal BaxSr1-xTiO3 Powders for Multilayer Capacitors Project Objectives Hydrothermal production of BaxSr1-xTiO3 powders Tape cast powders to form thin films Fabricate MLCCs from films Test dielectric properties of films and capacitors Review Capacitors BaxSr1-xTiO3 ceramics Tape casting Capacitors A capacitor is a device used to store potential energy in an electric field Typical capacitors consist of two conducting plates separated by a dielectric material Energy is stored as a result of the shifting of ions in the dielectric acting to oppose an applied electric field. Multilayered Ceramic Capacitors In parallel-plate capacitors C = ??oA / d For greatest capacitance, increase area and decrease thickness Capacitor size can be conserved by stacking many very thin capacitors BaTiO3 / SrTiO3 Ceramics Both have perovskite crystal structure, allowing the formation of a solid solution Have very high dielectric constants at their Curie Temperatures The curie temperature of the BaxSr1-xTiO3 can be controlled by the Ba / Sr ratio in the solid solution Tc of BaTiO3 is 120oC, Tc of SrTiO3 is –50oC Tape Casting Process to form thin, uniform sheets of ceramic material Ceramic powder mixed into an slurry containing solvent, binder, and dispersant. Slurry is cast into a soft, flexible green tape Solvent evaporation, binder burnout, and sintering are performed to obtain solid ceramic material Powder Production BaxSr1-xTiO3 powders produced using a hydrothermal process Reactions performed with solution properties: The ratio (Ba + Sr) / Ti = 2 (Ba +Sr) concentration of 0.8M NaOH concentration of 1M Typical yield of about 30g of powder from 500ml of solution Powder XRD Slip Composition Component BaxSr1-xTiO3 powder Hypermer KD-1 Methyl Ethyl Ketone Ethanol Acryloid B-72 Butyl Benzyl Phthalate Tape Casting Each of the final four powders was tape cast with a doctor blade height of 300 ?m Green tape thickness ranged from 110 ?m to 135 ?m Thickness varied up to 25