noteson lewis structuresand v s e p r- p c c(noteson路易斯结构和v s e p c r - p c).docVIP

noteson lewis structuresand v s e p r- p c c(noteson路易斯结构和v s e p c r - p c).doc

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LEWIS STRUCTURES AND VSEPR Group Atom Number of Bonds Or Valence Electron Configuration Or Valence Electrons Number of electrons needed for He/Ne electron configuration IV Carbon 4 2s2 2p2 4 V Nitrogen 3 2s2 2p3 3 VI Oxygen 2 2s2 2p4 2 VII Fluorine 1 2s2 2p5 1 Hydrogen 1 1s1 1 Rules for Drawing Lewis Structures (in priority order). 1. Calculate the total number of valence electrons from each atom in the molecule. a) positive ions: deduct one electron for each positive charge b) negative ions: add one electron for each negative charge. The number of valence electrons for atoms in groups I through VIII is equal to the Group Number The number of valence electrons for transition metal atoms is equal to the oxidation state of the atom 2. Arrange the atoms appropriately a) the central atom is usually the least electronegative. b) the molecule is usually symmetrical c) the molecular formula is usually drawn indicating the order of atoms, i.e. CH3CNO and CH3NCO have a different order of the carbon and nitrogen only. d) if you cannot obtain a reasonable Lewis structure (considering the number of bonds formed for each type of atom as in the table above), then merely try another arrangement of atoms. 3. Add lone pairs of electrons to satisfy the octet rule for each atom. Atoms from Period 2 (C, N, O, F) and higher take eight electrons. Be careful of: a) Hydrogen (H), an atom from Period 1 takes two electrons only instead of the eight. b) The electron deficient atoms, Be only takes a total of 4 electrons and B, 6 electrons instead of the usual eight. 4. Total the electrons in your structure, counting bonds (sticks joining atoms) as two electrons and lone pairs as two electrons. a) if the total electrons in your structure equals the total valence electrons, then you have a good structure. b) if the total electrons exceeds the number of valence electrons, then add a double bond (( bond) for each pair of electrons in excess of the valence. Not

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