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Reflectance changes in white reflectance standards measured in different instruments with 0/d geometry Joaquín Campos, Alicia Pons and Jorge Martín Instituto de Física Aplicada. CSIC. Spain Introduction Spectrophotometric errors in measurement of reflectance 0/d widely studied. Calibration standard (white standard) is assumed to be constant. 0/d reflectance measurement are done with an integrating sphere. Sphere error corrections Procedure developed at NPL: correction factors for the correct inclusion and exclusion of the specular component of reflectance. Specular beam exclusion error (gloss trap error) A gloss trap which does not completely eliminate light specularly reflected can lead to an error that depends on the specific instrument. Measuring the reflectance of a mirror in the specular excluded geometry Specular beam weighting error In many integrating spheres, light specularly reflected may not be evaluated with the same efficiency as light diffusely reflected. An error will be present in total reflectance measurements. Measuring the reflectance of a mirror in the specular included geometry Measurements Samples Glossy white ceramic tiles Matt white ceramic tiles Spectralon type white standards BCR matt white standards BCR glossy white standards Measurements Measurements Reflectance of every sample was measured (including and excluding the specular component) in the three instruments taking one of the matt standards as a reference, the same for all instruments Measurements Corrected reflectance: ?s instrument’s reading when sample is measured ?t instrument’s reading when reference is measured Rt reference standard’s reflectance (in practice not used) Ki correction coefficient for exclusion (i=2) or inclusion (i=3) of specular component ? and ? coefficients related to sample and standard, 1 for glossy specimens and zero for matt ones. Summary In specular included geometry, the adopted procedure allows to correct for the possible specular b
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