杂多酸型离子液体的合成及在清洁氧化中的应用.docVIP

杂多酸型离子液体的合成及在清洁氧化中的应用 摘 要 功能化离子液体是借由接入某些基团来实现某些催化性能或共催化性能。离子液体负载是获得离子液体催化性能主要方法，即将反应溶剂和催化剂合二为一。简化了反应及后处理过程。适用于均相反应，而共催化适用于非均相反应共催化性能产生的重大催化活性主要是离子液体和溶于其中的过渡金属催化剂之间的共催化作用，通过调整阴阳离子的种类和结构来优化所用的离子液体。然而，目前关于离子液体的理论体系还不成熟，开发功能化离子液体还存在显著地盲目性，尚需要实验辅助手段来试探，大大降低了研究和开发功能化离子液体的效率。 合成新型的杂多酸型离子液体BMAIH2PW12O40]，利用红外光谱、核磁共振波谱技术考察了该离子液体的结构，并采用热重技术考察了其热稳定性能。在此基础上将其用于离子液体BMAIH2PW12O40]—H2O2体系对模拟油（正辛烷，46-二甲基二本并噻吩）的氧化脱硫反应，并考察了其反应动力学。结果表明：当采用15 mL油样时，反应的最佳温度为40 ℃、H2O2用量为1.75 mL、离子液体用量为0.028 g，模拟油中46-二甲基二本并噻吩的脱硫率可达到95.5%；催化剂重复使用五次之后，催化活性基本不变；离子液体具有良好的稳定性；氧化反应为一级反应，其表观活化能Ea为31.55 KJ/mol指前因子K0为2.36×104 min-1。 关键词：磷钨酸离子液体，催化氧化脱硫，模拟油，反应动力学 Synthesis of Heteroplyacid Inioc Liquids and their application in clean oxidation Abstract unctional ionic liquid gets its catalytic performance or co-catalytic properties. The load of Ionic liquid of the main way to get the catalytic properties is applicable to the homogeneous reaction, just combines the reaction solvent and the catalyst, which simplifies the reaction and the post-treatment process. And co-catalytic is more applicable to heterogeneous reaction,the significant catalytic activity of co-catalyst is generated from the effect of the ionic liquid and dissolve in transition metal catalyst. We can optimize the ionic liquid by adjusting the type and struction of the anoin and cation. However,the theoretical system of flxnctionalized ionic liquid is not yet ripe, which still exits significant blindness. The task-specific ionic liquid needs auxiliary experimental to tentative lead to greatly reduce the efficiency of research and development of functional ionic liquid. Oxidative desulfurization of dibenzothiophene and other sulfides in ionic liquid for model oil（Octane, 4,6-Dimethyldibenzothiophene）was investigated oPhosphotungstic -based ionic liquid BMAIH2PW12O40].The optimal reaction conditions are as follows: reaction temperature of 40℃,15mL oil sample, 1.75mL hydrogen peroxide heteropoly acid type ionic liquid, Under this conditions, good d