杂多钼酸盐催化剂的合成.docVIP

摘 要 近年来，杂多酸催化剂的应用受到普遍关注，随着环保要求严格，杂多酸催化剂作为一种优良的多功能催化剂，既保持低温高性能，高选择性的优点，又克服了传统的氧化催化剂腐蚀设备的缺点。杂多酸可以称得上是一种绿色催化剂。 本文以12-钼硅酸、12-钼磷酸为母体酸，以六氢吡啶为有机配体合成了有机无机电荷转移配合物C5H10NH2)4SiMo12O40、[(CH2)5NH2]3PMo12O40。 通过元素分析，确认所合成的化合物，并与理论值较好地吻合。新合成的配合物的红外光谱数据在700～1100cm-1 范围内的吸收表明，配合物仍保留着多酸母体Keggin 结构骨架。与相应的母体酸比较，有一定程度的红移或者蓝移。这些数据表明，多阴离子与抗衡离子之间存在较强的相互作用。在1100～1580cm-1 区域是六氢吡啶环的振动吸收区，这些吸收峰证明了六氢吡啶的存在。 将新合成的杂多酸盐应用到苯甲酸的合成反应中取得了良好的效果，产率达到了96%。关键词：多金属氧酸盐电荷转移六氢吡啶苯甲酸 Abstract In recent years, the heteropoly acid catalyst application received the universal attention, was strict along with the environmental protection request, the heteropoly acid catalyst took one fine multi-purpose catalyst, both maintenance low temperature high performance, high selective merit, and overcame the traditional oxidative catalyst to corrode the equipment the shortcoming.The heteropoly acid may call on is one kind of green catalyst. Two organic/inorganic hybrid compounds (C5H10NH2)4SiMo12O40 1 and (C5H10NH2)3PMo12O40 2 have synthesized using 12-silicomolybdic acid and 12-phosphomolybdic acid and piperidine as raw materials. Through the ultimate analysis, confirmed synthesizes the compound, and tallies well with the theoretical value.The new synthesis preparation infrared spectrum data indicated in the 700~1100 cm-1 scope absorption that, the preparation was still retaining the sour parent substance Keggin structural framework.Compares with the corresponding parent substance acid, has certain degree red shift or blue moves.These data indicated that, between the multi-anions and the counter ion have the strong mutual function.In the 1100~1580cm-1 region is the hexahydropyridine link vibration absorption area, these absorption peak has proven the hexahydropyridine existence. Newly will synthesize the heteropoly acid salt applied the benzoic acid in the building-up reactions to obtain the good effect, the production rate has achieved 96 %. Keywords: polyoxometalate; charge-transfer; piperdine; benzoic acid