湿法提取五氧化二钒的工艺研究.docVIP

湿法提取五氧化二钒的工艺研究 摘 要 本文研究了从绿泥石中提取五氧化二钒的最佳工艺及最佳工艺条件。首先，对陕西某地的绿泥石进行了焙烧和室内浸出试验，确定了该矿石经预处理后矿石浸出率提高的条件，同时也确定了浸出率与浸出时间、温度、液固比和焙烧过程的相互影响条件，并且试探性研究了从绿泥石中无污染地提取五氧化二钒的工艺。最后，根据试验的结果并结合原矿石的性质选定最佳工艺，即采用钠盐焙烧－水浸的工艺。根据原矿石的性质和实验中钒的转浸特点，本文还采用萃取-反萃取的提钒方法。本文确定的提钒工艺具有污染小、工艺操作简便、生产工艺稳定、工作环境好、易于实现自动控制等优点。 关键词：绿泥石；五氧化二钒；焙烧；浸泡；萃取；沉钒；污染小 Study on Extraction of Vanadium Pentoxide from Chlorite Specialty ：Applied Chemistry ABSTRACT A technology for recovering V2O5 from chlorite and the optimum process conditions are described in this article. The mineral of chlorite carried in Shan’xi is roasted and leached after preparing in the experiment; then this paper makes sure the conditions of leaching for exaltation, and studies on the rate of leach to leach times ,temperature, roasting process and so on ，and extraction of V2O5 from chlorite containing Vanadium is investigated. Finally, this paper makes sure the optimum technology recovering V2O5 from chlorite with the properties of the mineral and the rate of vanadium conversion. In this article, the recovering of V2O5 by roasting with Na2CO3-water leaching is the optimum technology. This paper also uses the extract and the counter-extract. This method pollutes slightly, the craft operation is simple, and the production craft is stable, process conditions is good and easy to realize the automatic control. KEY WORDS: Chlorite, Vnadiumpentoxide, Roasting, Leaching, extract, sink vanadium, pollute slightly 目 录 中文摘要.................................................... (ⅰ) 英文摘要... .................................................(ⅱ) 1前言........................................................（1） 1.1钒与钒化合物...................... ... ... ... ... ... ..（1） 1.2提钒工艺简述.......................... ... ..............（1） 1. 3国内外的研究状况及发展趋势............................. （3） 1. 4提取五氧化二钒的新技术............ .....................（3） 1.5本课题的选题意义.......................................（5） 2实验部分与检测方法...................... ... ........