水基流延成型制备Ni-Cu-Zn软磁铁氧体薄磁片及其磁学性能研究.doc

添加Bi2O3对水基流延成型制备NiCuZn软磁铁氧体薄磁片磁学性能的影响 马 腾，熊兆贤*，翁章钊，徐文浩，冯 瑶 （厦门大学材料学院，福建 厦门 361005） 摘要：采用水基流延成型工艺制备Ni0.33Cu0.23Zn0.44BixFe2-xO4（x = 0，0.005，0.010，0.015，0.020，0.025，0.030）的铁氧体坯片。研究了不同Bi含量的NiCuZn铁氧体样品在1~ 200 MHz频率范围内的磁谱和频率在100 kHz下磁导率温度系数αμ,；结果表明，随着Bi含量的增多，铁氧体样品在13.56 MHz下的磁导率先升后降，截止频率先降后升；在x=0.020时磁导率达到最大值为213.71，截止频率最小；且随着Bi含量增大，磁导率温度系数由正值转为负值，磁导率温度系数绝对值〡αμ〡°C的低温环境下烧结，保温3 h即可获得高磁导率和磁导率温度系数较小的NiCuZn铁氧体，可用做NFC铁氧体隔磁片。 关键词：水基流延成型；NFC铁氧体；温度稳定性；磁导率；低温烧结 中图分类号：TM 277+ 文献标志码： A Influence of Bi2O3 Additive on Magnetic Properties of NiCuZn Ferrite Films Prepared via Aqueous Tape casting Technology MA Teng, XIONG Zhao-xian*, WENG Zhang-zhao, XU Wen-hao, FENG Yao （College of Materials ,Xiamen University, Xiamen 361005,China） Abstract: Ferrite films with different Bi contents of Ni0.33Zn0.44Cu0.23BixFe2-xO4（x=0, 0.010, 0.015, 0.020, 0.025, 0.030）were prepared via aqueous technology of tape casting . The complex permeability spectra with different Bi contents were investigated under 1-200 MHz and the temperature coefficient of permeability under 100 kHz was studied. The results revealed that the initial permeability increased first and then decreased with the increasing of x under the frequency of 13.56 MHz, which showed the contrary trend of the cut-off frequency; and the initial permeability reached the maximum value of 213.71，but the cut-off frequency attained the minimum value of 19.4 MHz when x was 0.020. The coefficient of initial permeability changed from positive to negative, nevertheless, the absolute value of αμ decreased firstly and then increased. The low permeability temperature-coefficient and high permeability of Ni0.33Cu0.23Zn0.44BixFe2-xO4 ferrite films were obtained with x ranging 0.015 to 0.02 and when being sintered at low temperature of 960 °C for 3 h, which turned out to be suitable for the application of NFC. Key words: aqueous tape casting technology; NFC ferrite; temperature stability; permeability; low temperature sinte