Measuring the Solubility of Ligated Gold 测量连接金的溶解度.pptVIP

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Measuring the Solubility of Ligated Gold 测量连接金的溶解度.ppt

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Measuring the Solubility of Ligated Gold 测量连接金的溶解度

Measuring the Solubility of Ligated Gold Nanoparticles in Hydrocarbon Solvents By Jeffrey Powell Physics REU Summer 2009 Partially Funded Through NSF Nanotechnology Reside at the edge of quantum mechanics and condensed matter Can act and behave as a “supermolecule” Large ratio of surface area to volume Tip of the Iceberg Synthesis of Gold Nanoparticles Inverse Micelle Method-Soaps and Salts Reduction of Gold Salt to grow nanocrystals Ligands added to stabilize Micellar Diffusion structures nanocrystals Digestive Ripening Reflux solution of polydisperse particles Forms monodisperse solution Alkane Ligated Gold Particle Solubility Tests Dissolved in alkane solvents Centrifuge at 12000g acceleration Take UV-Vis absorbance data on the supernatant Raw data converted into concentration of gold in solution Data Data “Like Dissolves Like” Thiol chain length influences solubility Gold concentration peaks where solvent similar to ligand Data Data “Like Does Not ALWAYS Dissolve Like” Peaks not where expected Unknown forces at work Struggles Separation of two-phase system Melting point of hexadecane thiol Stability of particles Conclusion Suspension of particles acting as a thermal reversible solution Future Work * * Post Digestive Ripening Pre Digestive Ripening Au Au3850(C12SH)350 *