Nano Mechanics and Materials Theory, Multiscale Methods and纳米力学与材料理论多尺度方法.pptVIP

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Nano Mechanics and Materials Theory, Multiscale Methods and纳米力学与材料理论多尺度方法.ppt

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Nano Mechanics and Materials Theory, Multiscale Methods and纳米力学与材料理论多尺度方法

Nano Mechanics and Materials:Theory, Multiscale Methods and Applications by Wing Kam Liu, Eduard G. Karpov, Harold S. Park 4. Methods of Thermodynamics and Statistical Mechanics Definition and Features the Thermodynamic Method Classification of Thermodynamic Parameters Internal and External Parameters: Examples State Vector and State Equation Analysis of the State Equation: System Parameters Examples of the State Equation The Postulate on Existence of Temperature The First Law of Thermodynamics The Second Law of Thermodynamics Entropy The Third Law of Thermodynamics Thermodynamic Potentials 4.1 Basic Results of the Thermodynamic Method Hamiltonian Mechanics Micromodel vs. Macromodel 4.2 Statistics of Multiparticle Systems in Thermodynamic Equilibrium Statistical Description of Mechanical Systems Statistical Description of Mechanical Systems Distribution Function Statistical Ensemble Statistical Averaging Ergodic Hypothesis and the Time Average Law of Motion of a Statistical Ensemble Equilibrium Statistical Ensemble: Ergodic Hypothesis Canonical Ensembles Microcanonical Distribution Microcanonical Distribution: Integral Over States Microcanonical Distribution: Integral Over States Microcanonical Ensemble: Illustrative Examples Harmonic Oscillator: Hamiltonian Harmonic Oscillator: Equations of Motion and Solution Harmonic Oscillator: Total Energy Harmonic Oscillator: Phase Integral Harmonic Oscillator: Entropy and Temperature Pendulum: Total Energy Pendulum: Phase Integral Pendulum: Entropy and Temperature Summary of the Statistical Method: Microcanonical Distribution Canonical Distribution: Preliminary Issues Canonical Distribution: Preliminary Issues Canonical Distribution Canonical Distribution: Partition Function Partition Function and Thermodynamic Properties Free Energy and Isothermal Processes Canonical vs. Microcanonical: Factorization of the Partition Function Factorization of the Partition Function: Computational Issues Analytical Example: Non-Interactive