Solubility Product Principle Academic Computer Center溶解度积原理学术计算机中心.pptVIP

PGCC CHM 102 Sinex Sinex CHM 102 Solubility Product Principle Dealing with the equilibrium of sparsely soluble solids How do we deal with solids? The solids are only slightly soluble (very little dissolves in water). What does dissolve behaves as a strong electrolyte (100% dissociation). Solutions become saturated and solid may remain at bottom of container. Can solubility be manipulated? Let’s consider silver chloride AgCl (s) ? Ag+ + Cl- What is the equilibrium constant? Ksp = (Ag+) (Cl-) Now what about the value of the Ksp? Ksp = 1.6 x 10-10 Can we calculate the solubility, s? Write the dissociation of the solids and the Ksp expressions AgBr (s) ? CaF2 (s) ? Fe(OH)3 (s) ? What is the pH of a bottle of Milk of Magnesia, a common antacid? Milk of Magnesia is Mg(OH)2 with Ksp = 8.9 x 10-12 Mg(OH)2 (s) ? Mg++ + 2OH- What happened in the beaker? AgI (s) ? Ag+ + I- dissolves to saturate the aqueous NaI solution with AgI However, after time passes, the radioactive I- is found in the solid AgI. The process is dynamic, as AgI is constantly dissolving and crystallizing. What influences the solubility? What would happen if we added HCl to the AgCl solution? What would happen if we added NH3 to the AgCl solution? The formation of complex ions Ammonia will react with silver (I) ion: * PGCC CHM 102 Sinex s s s = s2 s = (Ksp)1/2 = 1.3 x 10-5 M Ag+ + Br- Ca++ + 2F- Fe+3 + 3OH- Ksp = (Ag+)(Br-) Ksp = (Ca++)(F-)2 Ksp = (Fe+3)(OH-)3 s s 2s Ksp = (Mg++)(OH-)2 = s(2s)2 = 4s3 s = (Ksp/4)1/3 = 1.3 x 10-4 M (OH-) = 2s = 2.6 10-4 M pOH = 3.58 pH = 10.42 Would the solubility of AgI be the same or different in a solution of NaI? If different, how? To address this you need to write a reaction and consider Le Chatelier’s principle- AgI(s) ? Ag+ + I- The addition of the NaI causes the reaction to shift to the left. Hence the solubility decreases! A beaker with NaI, where the aqueous I- is radioactive, and a cr