Determination of Dioxins in Blood Using Nano-baskets Doped in Emulsion Liquid Membranes.pdf
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Determination of Dioxins in Blood Using Nano-baskets Doped in Emulsion Liquid Membranes.pdf
Chem.Res.Chin.Univ.2013,29(1),30—36 doi:10.1007/s40242-013-2048-4
DeterminationofDi1ooxinnssin‘Bl1oooodUUssiinng
Nano.basketsDopedinEmulsion
LiquidM embranes
MOKHTARIBahram andPOURABDOLLAH Kobra
RaziChemistryResearchCenter CRC),ShahrezaBranch,lslamicAzadUniversity,Shahreza,Iran
Abstract Extractionofdioxinsfrom bloodsampleswascarriedoutbyinclusion-facilitatedemulsionliquidmem-
braneprocess.Thenoveltyofthisworkistheapplicationofnano-basketsofcalixareneandemulsionliquidmem-
branesintheselectiveandemcientpreconcentrationofdioxin.Forthisaim.fourderivativesofP—tert-calix[4]arene
beraing differentsulofnamidemoietiesweresynthesized andtheirinclusion-extractionparameterswereoptimized
includingthecalixraene’sscaffoldandconcentration(asthecarrier/demulsifier),thediluenttypeinmembrane,the
phasenadthetreatratio.mixingspeed.and initialsoluteconcentration.Determinationswerefollowed by agas
chromatographna dtheresultsrevealthatundertheoptimizedoperatingconditions,thepreconcentrationofdioxins
wasimprovedandthemethodachievedlowerlimitofdetections(L0Ds).Underoptimalconditions,thefiguresof
meritsweredeterminedtobeL0D 1.0pg/L,dynamicrange0.6— 112.0pg/L,RSD5.5%(,z5),andthemaximum
enrichmentfactornadrecoveryweredeterminedtobe3.3and99%.respectively.
Keywords Nnao.basket;Dioxin;Inclusion;Calixraene;Emulsionliquidmembrna e
1 lntrOductiOn since dioxins rae fat.soluble nad readily climb the ofod
chain ,jJ.DioxinshavealsobeendetectedintyNcalcigraette
Priortoindustrialization,dioxinswithlow concentrations smoket. Dioxinsraeabsorbedprimrailythroughdietaryintake
formedinnatureduetogeologicalproc
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