Some spatial effects observed in the axially viewed filament argon microwave induced plasma with solution nebulization.pdfVIP
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Some spatial effects observed in the axially viewed filament argon microwave induced plasma with solution nebulization.pdf
Spectrochimica Acta Part B 57 (2002) 853–863
Some spatial effects observed in the axially viewed filament argon microwave induced plasma with solution nebulization
Krzysztof Jankowski*
Department of Analytical Chemistry, Faculty of Chemistry, Warsaw University of Technology, 00-664 Warsaw, Poland
Received 31 October 2001; accepted 6 February 2002
Abstract
Spatial profiles of analyte emission in an axially viewed argon filament microwave induced plasma sustained in the TE101 rectangular cavity have been measured along a discharge tube cross-section for neutral atoms as well as ion lines of several elements. The filament diameter was approximately 1 mm. The analyte solution was introduced by means of an ultrasonic nebulizer without desolvation. The radial emission distribution depends on the operating parameters and is different for each of the analytes examined. Spatial distributions of excitation temperature (4000– 6000 K) measured with Ar I lines by the Boltzmann plot method as well as electron temperature (6000–8000 K) by line to continuum emission ratio measurements at Ar I 430 nm and electron number density (1–1.5=1015 cmy3) by the Stark broadening method of the Hb line were determined to support the evidence of plasma processes. In the presence of excess sodium the enhancement of emission intensity and its shift to the plasma center appears to be the result of increased analyte penetration to the plasma. Changes in spatial emission profiles for Ca atoms and ions suggest that for this element ambipolar diffusion may be important as an additional interference mechanism. A possibility of minimizing spectral interferences from argon emission lines by choosing an off-axis plasma region for emission intensity measurements is indicated. ? 2002 Elsevier Science B.V. All rights reserved.
Keywords: Atomic emission spectrometry; Microwave induced plasma; Spatial emission profiles; Excitation mechanisms
1. Introduction
Spatial inhomogeneity in emission intensity distributi
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