Temperature and potential-dependent structural changes in a Pt cathode electrocatalyst viewed by in situ XAFS.pdfVIP
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Temperature and potential-dependent structural changes in a Pt cathode electrocatalyst viewed by in situ XAFS.pdf
Journal of Non-Crystalline Solids 354 (2008) 4227–4232
Contents lists available at ScienceDirect
Journal of Non-Crystalline Solids
journal homepage: /locate/jnoncrysol
Temperature and potential-dependent structural changes in a Pt cathode
electrocatalyst viewed by in situ XAFS
Agnieszka Witkowska a,*, Emiliano Principi b, Andrea Di Cicco b,1, Sonia Dsoke c, Roberto Marassi c, Luca Olivi d, Massimo Centazzo d, Valerio Rossi Albertini e
a Department of Solid State Physics, Gdansk University of Technology, 80-952 Gdansk, Poland b CNISM, CNR-INFM SOFT, Department of Physics, University of Camerino, I-62032 Camerino (MC), Italy c Chemistry Department, University of Camerino, I-62032 Camerino (MC), Italy d ELETTRA Sincrotrone Trieste S.C.p.A., 34012 Basovizza, Trieste, Italy e ISM-CNR, via del Fosso del Cavaliere, 100, 00133 Roma, Italy
article info
Article history: Available online 8 August 2008
PACS: 61.46.+w 61.10.Ht 82.45.Yz
Keywords: Nanoparticles Colloids and quantum structures
abstract
The paper presents an X-ray absorption ?ne structure (XAFS) investigation of Pt supported on Vulcan XC72 operating as a cathode catalyst in a polymer electrolyte membrane fuel cell (PEM FC). XAFS spectroscopy was performed in situ using a cell developed by the authors and optimized for absorption measurements. Low-noise spectra were obtained using the transmission mode over the Pt L3 XAFS range, enabling multiple-scattering XAFS data-analysis for the Pt nanocrystalline system under operating conditions. Accurate measurements of the local structure were performed at various potentials and working temperatures. Changes in the near-edge structures re?ecting variations in the Pt electronic structure were observed for various potential values in the cathode activation region. The Pt average local geometric structure was found to be practically potential-independent. The increase in structural disorder caused by the higher working FC temperature was not found to affect the catalyst’s perfo
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