共沉淀法制备LiNi01Co01Mn18O4及其电化学性能的研究.pdfVIP

共沉淀法制备LiNi Co Mn O 及其电化学性能的研 0.1 0.1 1.8 4 究 唐致远1 余明远1 薛建军2 高飞1 崔燕2 (1天津大学化工学院，天津 300072；2.广州鹏辉电池有限公司，广东 广州 511483) 摘要：用液相共沉淀法合成前驱体混合物，将该混合物在不同的焙烧条件下合成 LiNi Co Mn O 。使用原 0.1 0.1 1.8 4 子吸收光谱、扫描电子显微镜对合成材料的化学成分和结构进行了表征。将此材料作为锂离子电池正极活性 材料，用交流阻抗和充放电测试的电化学测试方法对材料进行了电化学性能的研究。实验结果表明，采用 300℃ 预焙烧，再经 750℃焙烧所制备材料结晶度更高，表面颗粒较大；充放电测试表明，采用二次焙烧所制材料 的循环性能优于一次焙烧所制材料。 关键词：LiNi Co Mn O ；共沉淀法；电化学性能 0.1 0.1 1.8 4 Synthesis and Electrochemical Characteristics of LiNi0.1Co0.1Mn1.8O4 1 1 2 1 2 TANG Zhi-yuan , YU Ming-yuan , XUE Jian-jun , GAO Fei , CUI Yan (1. School of Chemical Engineering and Technology, Tianjin University ,Tianjin 300072,China; 2. Guangzhou greatpower battery Co.,Ltd.Guangzhou,Guangdong 511483,China) Abstract: LiNi0.1Co0.1Mn1.8O4 materials were synthesized by firing the mixture of precursor which was prepared by co-precipitation under different conditions. AAS and SEM were adopted to evaluate the chemical composition, crystaline structure. The as-prepared powders were used as positive materials for lithium-ion battery, whose discharge capacity and EIS properties were examined. The results showed that LiNi Co Mn O calcined in 300 ℃ in advance has better particle morphology and 0.1 0.1 1.8 4 cyclic performance than that of the uninterrupted-combustion product. Key words: LiNi Co Mn O ; co-precipitation method; electrochemical performance 0.1 0.1 1.8 4 锂离子电池由于具有高能量密度、高电动势及低自放电等优良特性，已被广泛应用于移