填充型Hβ分子筛聚砜复合膜的制备与性能研究.pdfVIP

填充型H-?分子筛-聚砜复合膜的制备与性能研究 * 彭春艳 赵晓燕 张欧妮 黄震 郭玉花 滕立军 （天津商业大学材料科学与化学工程研究所包装工程系，天津 300134） [摘要] 本文以聚砜为基体材料填充H-?分子筛，制备一系列的新型聚合物基复合膜，考察了这些膜 的微观形貌，力学性能和气体渗透性能。结果表明，分子筛加入后与聚合物之间形成较好的界面结合，但 是复合薄膜的拉伸强度明显降低，与分子筛的含量近似为线性关系。O 、N 和 CO 三种气体的渗透测定 2 2 2 结果显示表明，加入分子筛后，这些气体的渗透系数显著上升，而且随着分子筛含量的增大而进一步提高。 聚砜基复合膜中的H-? 分子筛含量为20wt% 时，对O2 与N2 的渗透系数提高了近60% ，而对CO2 的渗透 系数净增了96%。同时复合膜对CO / N 和CO / O 的分离选择性也有较大的提高。这些结果表明，加入 2 2 2 2 分子筛后，至少有部分气体分子是经过分子筛的孔道吸收与扩散而实现膜的透过的，即H-?分子筛起了筛 分作用。可以推论填充分子筛改变了聚合物本体材料的内部结构，进而改善其气体渗透性能，有助于实现 气体成分的调控或气体分离。 关键词：H-?分子筛；聚砜；复合膜；气体渗透性能；拉伸强度 Preparation and Property Investigation of H- βZeolite-filled Polysulfone Composite Membranes Chun-yan Peng, Xiao-yan Zhao, Ou-ni Zhang, Zhen Huang*, Yu-hua Guo, Li-jun Teng (Department of Packaging Engineering, Institute of Materials Science and Chemical Engineering, Tianjin University of Commerce, Tianjin 300134) Abstract：With polysulfone as substrate materials, a series of new polymer -based composite membranes were fabricated by adding H-?zeolite particles . These membranes were examined by observing micro-structural morphology, testing gas permeation and investigating mechanical property. Experimental results show that H-? zeolite particles could be finely dispersed in the poly sulfone matrix with nice organic -inorganic interfacial compatibility at low zeolite loadings . The resultant membranes are found to have lower tensile strength than the neat polysulfone film and the tensile strength is approximately linearly decreasing with the zeolite content. The gas permeation tests s