用于质子交换膜燃料电池的新型抗溺水性电极.pdfVIP

用于质子交换膜燃料电池的新型抗溺水性电极 1，2 1，2 1，2 1，2 1，2 1 季孟波 ，陈四国 ，李莉 ，王耀琼 ，张 骞 ，魏子栋 1 2 （重庆大学化学化工学院，重庆400030 ； 重庆大学材料科学与工程学院，重庆400030 ） 摘要：制备了一种含有防水油——二甲基硅油（DMS ）的新型抗溺水性电极（AFE ），含有AFE 阴极的质 子交换膜燃料电池（PEMFC ）无论在水淹状态下还是在正常运行条件下均显示了优于仅由传统 Pt/C 电极 （CPE ）组成电池的性能。AFE 所体现的这种抗水淹性能主要源于氧在DMS 中的溶解度至少是在水中溶解 度的10 倍，DMS 在孔隙中为氧的传输提供了一种永不被水占据的通道。 关键词：抗溺水；质子交换膜燃料电池；电位反转；水淹；防水油 中图分类号：TQ 文献标识码：A 文章编号： A novel anti-flooding electrode for proton exchange membrane fuel cells 1，2 1，2 1，2 1，2 1，2 JI Mengbo ，CHEN Siguo ，LI Li ，WANG Yaoqiong ，ZHANG Qian ， 1 WEI Zidong 1 ( School of Chemistry and Chemical Engineering ，Chongqing University，Chongqing 400030 ，China； 2 School of Material Science and Engineering ，Chongqing University，Chongqing 400030 ，China) Abstract ：Water management in PEMFC is critical. Especially if excessive water produced at the cathode were not removed timely it would accumulate at the cathode and cause electrode flooding, further ruin PEMFC performance. Although the water flooding has been extensively studied, all measurements having been reported so far only involve the water removals accumulated at the gas flow channels of a bipolar plate. There are few reports that aimed to overcome water flooding happening in the pores of a porous electrode so far. The objective of this study is thus devoted to solve the water flooding happening in the pores of a porous electrode by using an anti-flooding electrode (AFE) which contains water-proof oil, dimethyl-sili