磷酸钛微孔晶体的合成与结构.pdfVIP

磷酸钛微孔晶体的合成与结构 赵永男，杨扬，杨小勤 (天津工业大学材化学院，天津市改性与功能纤维重点实验室，天津300160，中国) 摘 要：由于过渡金属配位环境、价态的多样性以及多种金属氧簇的形成，使过渡金属磷酸盐微孔材料得到 迅速发展，特别是还原态金属的存在将提高微孔材料氧化催化性能，但是作为磷酸盐的重要成员，磷酸钛微 孔晶体的发展严重滞后，本文采用金属钛粉为原料，控制反应速度并创造还原性氛围，利用不同有机胺为结 构导向剂，合成了三种新型结构的混合价磷酸钛化合物，其中化合物1为一维链状结构，化合物2和3为具有 12元环孔道结构的微孔晶体。健价计算表明，三种化合物中均含有三价钛，化合物2和3中存在两种钛原子， 分别为3价和4价，化合物1中只有一种钛原子，价态为3.5，磁性测试显示，化合物1中钛的有效μB为0.867。 关键词：水热合成；微孔晶体；磷酸钛；晶体结构 Syntheses and Structure of Microporous Titanophosphates ZHAO Yongnan, YANG Yang, Yang Xiaoqin (College of Materials Science and Chemical Engineering Tianjin Key Laboratory of Fiber Modification and Functional Fiber, Tianjin Polytechnic University, Tianjin 300160, P.R. China.) Abstract ： Microporous transition metal phosphates experienced dramastic development due to the diversities of coordinations, valence and various aggregates of polyoxometalates. Particularly, the existance of reduced species enhanced the oxidic catalytic properties of microporous materials However, microporous titanophosphates, an important branch of phosphates, were limited in literature up to now. Here, three novel titanophosphates were synthesized by using titanium powder to control the reaction speed and create reducing environment. Various organoamines were used as trial templates. While compound 1 was a chain structure, compounds 2 and 3 were three-dimentional with 12-ring channels. Bond valence sum calculations revealed that the oxidant state of two crystallographic unique titanium in compound 2 and 3 were 3 and 4 respectively. The state of titanium in compound 1 was 3.5, which agreed with magnetic measurement (μB = 0.867). Keywords ：hydrothermal synthesis ；microporous crystal; titanophosphate; crystal structure. 金属磷酸盐微孔材料在催化及主客体化学领域的应用前景及特性使其备受关注并得到