磷钼酸喹啉重量法测定NiP镀层磷含量.pdfVIP

磷钼酸喹啉重量法测定Ni．P镀层磷含量 印仁和1薛雷刚1郁祖湛2 (1．上海大学化学系，上海2004442．复旦大学化学系，上海200433) 【摘要】介绍了磷钼酸喹啉重量法在镍磷镀层磷含量测定中的应用，与国家标准GB／T 13913--92分光光度法进行比较，本方法测定相对误差为一1．65％一4．21％，能用于准确测定镍 磷镀层磷含量；并与x射线能谱对本试验室Ni．P镀层进行对比测定，EDX所测结果比重量 法普遍偏高。 【关键词】磷钼酸喹啉重量法；镍磷镀层：磷含量；分光光度法；EDX of contentofNi—P the Determination Quinoline phosphorous depositby method phosphomolybdategravimetric YIN Zu．zhanz Ren．heI,XUE Lei—gan91．YU of 200444 of (1．DepartmentChemistry,ShanghaiUniversity,Shanghai2．Department Chemistry,FudanUniversity,Shanghai200433) [Abstract]Introducedthe ofthe methodin applicationQuinolinephosphomolybdategravimetric theDeterminationof contentofNi—P relativeerrorofthismethodis phosphorus deposit．The withnationalstandardGB／T13913-92 method． -1．65％-4．21％compared spectrophotometric in of on Thereforeitcailbeused contenttheEN carriedthe determiningphosphorus deposit；And ofEDXale withthe dispersive results comparisonenergy X-rayspectroscopy(EDX)．The alittle thanthe method Quinoline generallyhigher phosphomolybdategravimetric [Keywords]Quinolinephosphomolybdategravimetricmethod；Ni-P deposit；phosphorous method；EDX content；spectrophotometric 前言 化学镀Ni—P非晶态合金由于具有良好的耐蚀性，耐磨性，高硬度等优良的物理化学性能，