坩埚旋转波形参数对晶体组分偏析影响的数值研究.pdfVIP

第40卷 2004年9月 第9期 987—994页 金属学玫 ACTA METALLURGICA SINICA V01．40 Sept．2004 NO．9 PP．987—994 坩埚旋转波形参数对晶体组分偏析影响的数值研究 刘俊成 (山东理工大学材料科学与工程学院，淄博255091) 木 摘 要 计算模拟了加速坩埚旋转技术Bridgman(ACRT—B)法生长Cd0．96Zn0．04Te单晶体过程，研究了ACRT波形 参数对固一液界面凹陷和晶体内组分偏析的影响．计算结果表明： ACRT波形参数的变化几乎不影响固一液界面前沿熔体中均 一浓度场的形成．但是，波形参数能够显著改变固_液界面的凹陷和晶体内的组分偏析．波形参数不适当时，固一液界面的凹陷 深度增加数倍，同时晶体组分的径向偏析也显著增加．波形参数不适当时，固一液界面的凹陷深度不增加或增加很少，晶体组分的 径向偏析显著减小，直至为零．本工作所选择的各种波形参数下， ACfⅡ’均能明显增加晶体组分的轴向偏析． 关键词 Cd—Zn—Te晶体，组分偏析，数值模拟，传热传质，加速坩埚旋转技术 中图法分类号TN304．053，0782 文献标识码 A 文章编号0412-1961(2004)09—0987—08 SIMULATIoN oF EFFECT oF CRUCIBLE RoTATIoN PARAMETER oN SINGLE CRYSTAL SoLUTE SEGREGATIoN L1 U Juncheng School of Materials Science and Engineering，Shandong University of Technology，Zibo 255091 Correspondent：LIU Juncheng，professor,Tel：(05ss)2773385，Fax：(05ss)2773385， E—mail：ichliu2002@yahoo．corn．cn Supported by National Natural Science Foundation o|China NoI and Natural Science Foundation of Shandong Pmvince(No．Y2000G07 l Manuscript received 2003—10—10．in revised foFlTI 2004—02—08 ABSTRACT A numerical simulation was carried out for Cd0．96Zno．04Te crystal growth using vertical Bridgman method fVBMl．E艉cts wave parameters of the accelerated crucible rotation technique fACRTl on the solid—liquid interface concavity and the solute segregation were investigated．The results show that for the foor kinds of wave parameters．the AC R!T results in an uniform solute concentration field in the melt in the front of the solid—liquid interface．However，ACRT wave parameter has crucial effects on both the solid—liquid interface shape and the solute segregation in the crystal．With a suitable wave parameter．the ACRT can make the solid—liquid interface concavity increase a little，or even not increase，and decrease the radial solute segregation in the single crystal extraordinarily，even to be equal to zero．On the contrary．with an unsuitable wave parameter the ACRT can make the solid—liquid interface concavity increase in a great deal，even up to six times，and