5.g-C3N4光催化性能的进展14年8月讲义.pdfVIP

第 29卷 第 8期 无 机 材 料 学 报 Vol. 29 No. 8 2014年 8月 Journal of Inorganic Materials Aug., 2014 收稿日期: 2013-12-04; 收到修改稿日期: 2014-01-16 基金项目: 国家自然科学基金; 湖南省自然科学杰出青年基金(14JJ1001) National Natural Science Foundation of China ; Hunan Provincial Natural Science Foundation for Disting uished Young Scholars(14JJ1001) 作者简介: 楚增勇(1974–), 男, 博士, 研究员. E-mail: chuzy@nudt.edu.cn 文章编号: 1000-324X(2014)08-0785-10 DOI: 10.15541/ji g-C3N4 光催化性能的研究进展 楚增勇，原 博，颜廷楠 (国防科学技术大学 理学院, 长沙 410073) 摘 要: 利用光催化剂将太阳能转化为人类可以直接利用的能量, 并用其解决地球资源的枯竭和生存环境的恶化是 可再生清洁能源研究的一个方向。g-C3N4的独特结构赋予其良好的光催化性能, 使之成为光催化领域的研究热点。 目前在光催化领域, g-C3N4主要用于催化污染物分解、水解制氢制氧、有机合成及氧气还原。在实际应用中, 为进 一步提高 g-C3N4 的光催化效果, 科研工作者开发了多种改进方法, 例如物理复合改性、化学掺杂改性、微观结构 调整等。本文主要论述了 g-C3N4在光催化领域的应用以及光催化性能的改进方法, 简要阐述了光催化和各种改进 方法的机理, 分析了目前 g-C3N4在光催化领域面临的问题和挑战, 展望了 g-C3N4的应用前景。 关 键 词: g-C3N4; 光催化; 改进方法; 综述 中图分类号: TB321 文献标识码: A Recent Progress in Photocatalysis of g-C3N4 CHU Zeng-Yong, YUAN Bo, YAN Ting-Nan (College of Science, National University of Defense Technology, Changsha 410073, China) Abstract: Based on photocatalysts, solar energy can be converted into the energy that human can directly utilize, so as to solve the problems such as the depletion of the Earth’s resources and the deterioration of living environments. The unique structure of g-C3N4 gives it good photocatalytic performance. Its development and utilization have been a research hotspot recently. Generally, g-C3N4 can be used in the degradation of pollutions, hydrolysis to generate hy- drogen and oxygen, organic synthesis and oxygen reduction. However, in practical, its performance is not satisfactory. Researchers have tried many new methods to improve its photocatalysis, which include physical coupling modification, chemical bonding modification and microstructural modification. The review summarizes its photocatalysis and im- proving methods, briefly illustrates the catalysis mechanism,