有机化学Chapter3.Alkenes烯烃综述.pptVIP

(1) 卤化反应 烯烃与卤素在高温下发生α –卤代反应： 这是自由基反应 反应机理： 链引发 链传递 反应条件：h 或 ROOR 使用一些试剂，可在温和的条件下进行 α –卤代反应。 环己烯 NBS 3–溴环己烯 丁二酰亚胺 N–溴代丁二酰亚胺(NBS) ν Additional problems: 1.Vinylcyclopropane reacts with HBr to yield a rearranged alkyl bromide.Follow the flow of electrons as represented by the curve arrows, show the structure of the intermediate in brackets, and show the structure of the final product. 2. Predict the products of the following reactions. Don’t worry about the size of the molecule, concentrate on the functional groups. Cholesterol ( 胆固醇) 作业：Prof. Zhang’s book