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A study on mechanism of corrosion protection of polyaniline coating and its failure.pdf

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A study on mechanism of corrosion protection of polyaniline coating and its failure

Corrosion Science 49 (2007) 4232–4242 /locate/corsciA study on mechanism of corrosion protection of polyaniline coating and its failure Jianjun Fang, Ke Xu, Lihua Zhu *, Zhixiong Zhou, Heqing Tang * Department of Chemistry and Chemical Engineering, Huazhong University of Science and Technology, Wuhan 430074, PR China Received 27 November 2006; accepted 1 May 2007 Available online 19 July 2007Abstract Polyaniline (PANI) coatings were electrochemically deposited on substrates of stainless steel and platinum in solutions of 0.2 M H2SO4 and 0.1 M aniline by cyclic voltammetry. The corrosion pro- tection of the PANI coatings and their failure were investigated in 0.2 M H2SO4 solution. It was observed that the corrosion protection ability of the coating to steel substrate was increased with the increase of the coating thickness. The corrosion protection ability was mainly attributed to the passivating effect of PANI due to its oxidizing ability in its emeraldine state. During its opera- tion, the PANI coating in emeraldine state tended to gradually lose its corrosion protection ability. This gradual failure of the PANI coating, but faster than expected, was confirmed to be related to a gradual reduction of the emeraldine PANI and a gradually increased resistance between the PANI coating and the stainless steel substrate. These findings lead to a new mechanism for the corrosion protection of PANI coating and its failure. 2007 Elsevier Ltd. All rights reserved. Keywords: A. Polyaniline; A. Stainless steel; C. Corrosion; C. Electrodeposited films; C. Galvanic coupling1. Introduction Intrinsically conducting polymer, because of its specific properties, has a wide range of applications. One of the important and promising applications is corrosion protection.0010-938X/$ - see front matter 2007 Elsevier Ltd. All rights reserved. doi:10.1016/j.corsci.2007.05.017 * Corresponding authors. Tel.: +86 27 fax: +86 27 E-mail addresses: lhzhu63@ (L. Zhu), hqtang62